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Eri Widianto
Singaperbangsa Karawang
Earth & Planetary Sciences Electrical & Electronics Engineering Energy Materials Science & Nanotechnology Physics

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Characterization cyrstalinity, elements, and functional  groups of  hydroxyapatite shynthesized from sea urchin shell with annealing temperature variation Muhamad Nanda Abdullah; Kardiman Kardiman; Firda Aulya Syamani; Nur Indah Wulandari Sumarsono; Eri Widianto
Indonesian Physics Communication Vol 23, No 2 (2026)
Publisher : Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/jkfi.23.2.117-126

Abstract

This study aims to study the characteristics of hydroxyapatite (HAp, Ca10(PO4)6(OH)2) derived from sea urchin (Tripneustes sp.) shells via wet precipitation method with annealing temperature variations of 600°C (HAp600) and 900°C (HAp900). Raw materials used were calcium oxide (CaO) obtained from calcination of sea urchin shells at 1000°C as a calcium source, and diammonium hydrogen phosphate ((NH4)2HPO4) as a phosphate source, with precipitation at 60°C and pH 10 followed by 24-hour aging. Characterization was performed using X-ray diffraction (XRD), X-ray fluorescence (XRF), and Fourier transform infrared (FTIR). XRD results confirmed hexagonal HAp phase formation consistent with JCPDS No. 09-0432, with average crystal sizes of 19.359 nm (HAp600) and 42.636 nm (HAp900), demonstrating significant crystal growth with increasing annealing temperature. A secondary β-tricalcium phosphate (β-TCP) phase was detected in the HAp600 sample, indicating incomplete HAp transformation. XRF analysis showed Ca/P ratios of 1.80 (HAp600) and 1.76 (HAp900), with the HAp900 sample approaching the ideal HAp stoichiometric value (1.67). The relatively high magnesium (Mg) content (5–6%) is a natural characteristic of magnesian calcite from sea urchin shells. FTIR spectra identified phosphate groups (PO43-) at 1027–1028 cm-1 and 558–603 cm-1, and carbonate groups (CO32-) at 1408–1412 cm-1 indicating B-type carbonated hydroxyapatite formation.
Co-Authors Firda Aulya Syamani Kardiman Kardiman Muhamad Nanda Abdullah Nur Indah Wulandari Sumarsono