Erilia Yusnitha
Pusat Teknologi Bahan Bakar Nuklir – BATAN

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PENGARUH METODE PREPARASI BROTH DAN JENIS PREKURSOR ZIRKONIUM PADA KARAKTERISTIK KERNEL YTTRIA-STABILIZED ZIRCONIA (YSZ) Sarjono Sarjono; Etty Mutiara; Erilia Yusnitha; Winter Dewayatna
Urania: Jurnal Ilmiah Daur Bahan Bakar Nuklir Vol. 26 No. 1 (2020): Urania : Jurnal Ilmiah Daur Bahan Bakar Nuklir
Publisher : Badan Riset dan Inovasi Nasional

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17146/urania.2020.26.1.5743

Abstract

THE INFLUENCE OF SOL PREPARATION METHOD AND TYPE OF ZIRCONIUM PRECURSOR ON THE CHARACTERISTIC OF YTTRIA-STABILIZED ZIRCONIA (YSZ) KERNEL. Fabrication of yttria-stabilized zirconia (YSZ) kernel by external gelation method has been done. Urea was used in the broth preparation to serve as: 1) as homogenous precipitation agent to produce sol when added at decomposing temperature of urea and 2) as pore promoter when added at below decomposing temperatures of urea. The research used urea in varied mol urea/metal ratio to obtain an the optimum value based on the resulted morphological properties of the sintered kernel. The zirconium precursor used was zirconium oxynitrate hydrate. Characterization of the kernel products include examination with SEM to study the morphological properties of the dried and sintered kernels, measurement of diameter and density of the sintered kernel, and XRD examination to determine the phase of the resulted solid solution of zirconium-yttrium oxide. Based on themorphological examination, the optimized addition of urea according to its function: 1) as precipitation agent in the sol preparation, mol urea/metal ratio of 1.0 at decomposing temperature of 80oC and 2) as porosity generation in the gel microsphere, mol urea/metal ratio of 1.5 at addition temperature of 50oC. The XRD examination shows that a mixture of 16% mol yttrium nitrate dan 84% mol zirkonium nitrate has resulted in solid solution of Y0,15Zr0,85O1,93 or 92ZrO2.8Y2O3 kernels with cubic phase. Increase in precursors concentration in broth has resulted in increase in the diameter of the sintered YSZ kernel, where kernels with average diameter of 0,510 mm was obtained from 0,855 mol/L precursors in broth. Kernels with desired diameter can be prepared by tuning of precursors concentration in broth.
PENGARUH JENIS PACKING PADA MENARA PACKED-BED ABSORBER DALAM PENYERAPAN GAS NOx Agoeng Kadarjono; Erilia Yusnitha; Agus Sartono Dwi Santosa; Pertiwi Diah Winastri
Urania: Jurnal Ilmiah Daur Bahan Bakar Nuklir Vol. 26 No. 1 (2020): Urania : Jurnal Ilmiah Daur Bahan Bakar Nuklir
Publisher : Badan Riset dan Inovasi Nasional

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17146/urania.2020.26.1.5738

Abstract

THE EFFECT OF PACKING TYPE ON THE PACKED-BED ABSORBER IN ABSORPTION OF NOx. Design of NOx effluent gas processing needs to be done for broth preparation and gel casting activities in the UO2 kernel fabrication process series. The availability of this effluent processing tool will increase the economic value and process efficiency, reduce the amount of the chemicals needed, and minimize the hazards associated with toxicity and contamination. The design of the effluent processing tool chose the packed-bed absorber using NOx gas as a feed stream and water as an absorbent medium. The packed-bed absorber has been designed and calculated to determine the effect of various types of packing (pall, ralu, and nor-pac ring) for the absorbtion of the NOx gas. To determine the effect of the packing type, it is carried out by simulating fluid flow rate on diameter, effective surface area of packing, pressure drop, mass transfer coefficient, packing column height, and tower height by inserting into the appropriate equations using the EXCEL program. The inclusion of the effect of feed flow rate and type of packing in the calculation resulted in smaller diameter for the tower containing pall ring packing than the diameter of tower containing other fillings but gave higher pressure drop values, effective surface area of packing, total mass transfer coefficient, and tower height. Increase in NOx gas absorption causes an increase in the amount of packing space and tower height. Increase in operating pressure and temperature causes a decrease in packing and tower height, whereas increase in flooding factor, beside causing a decrease in packing and tower height, decreases the tower diameter. This type of pall ring packing is a design choice because it produces small/economic dimensions.