Fariati
Jurusan Kimia Universitas Negeri Malang

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Sintesis dan Karakterisasi Senyawa Kompleks dari Kadmium nitrat dan 1,3-bis(difenilfosfino)propana dengan Stoikiometri 1 : 1 Wawan Setiawan; Fariati; Effendy
JC-T (Journal Cis-Trans) : Jurnal Kimia dan Terapannya Vol. 1 No. 2 (2017)
Publisher : Universitas Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17977/um026v1i22017p019

Abstract

Coordination compound of cadmium nitrate and dppp has not been reported. The purpose of this research are to synthesize coordination compoound of cadmium nitrate and dppp with 1:1 stoichiometry and determine its structure. The coordination compound obtained is colourless cry stalline solid having beam shape with melting point of 272-275̊C. Results of electrical conductivity and qualitativeC fkekfksnitrate ion tesindicates that the compound is a molecular one. EDX analysisshow the empirical formula C27H26CdN2O6P2. The accepted compound is [Cd(ONO2)2(dppp)] with distorted tetrahedral structure and average free bond energy -47.5 kJ/mol.