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All Journal JC-T (Journal Cis-Trans) : Jurnal Kimia dan Terapannya
Husni Wahyu Wijaya
Jurusan Kimia, Fakultas Matematikan dan Ilmu Pengetahuan Alam, Universitas Negeri Malang
Biochemistry, Genetics & Molecular Biology

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Pengembangan katalis nikel-itrium oksida untuk konversi furfural sebagai senyawa turunan biomassa menjadi 1,5-pentanediol Husni Wahyu Wijaya; Shogo Shimazu
JC-T (Journal Cis-Trans) : Jurnal Kimia dan Terapannya Vol. 2 No. 2 (2018)
Publisher : Universitas Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17977/um026v2i22018p001

Abstract

Hydrogenolysis of biomass-derived furfural (FFR) to 1,5-pentanediol (1,5-PeD) is a critical route forsustaining fine chemicals. Development of nickel-yttrium oxide catalysts has been successfully synthesized with two different treatments. The first catalyst, Ni-Y(n)HT catalyst, was synthesized by direct reduction from nickelyttrium hydroxides mixture. The mixture of nickel-yttrium hydroxides from the same preparation procedure was calcined as a pretreatment and subsequence reduced using hydrogen gas giving Ni-Y2O3(n)T catalyst. The reduced of catalysts consists of nickel(0) and yttrium oxide with the difference in crystallinity. The difference in catalytic performance between both type catalysts showed in the production of 1,5-PeD from hydrogenolysis of FFR. Catalytic behavior of catalysts is similar and Ni(0)-Y2O3 boundaries is critical for cleavage C-O bond of furan ring.
Co-Authors Shogo Shimazu