Driejana, Driejana
Institut Teknologi Bandung

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Composition of Ions and Trace Metals in Rainwater in Bandung City, Indonesia Hasan, Nia Yuniarti; Driejana, Driejana; Sulaeman, Aminudin
IPTEK Journal of Proceedings Series No 6 (2017): The 3rd International Conference on Civil Engineering Research (ICCER) 2017
Publisher : Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (173.612 KB) | DOI: 10.12962/j23546026.y2017i6.3310

Abstract

The basin shape of Bandung limits dispersion and transport of air pollutants. This topographical characteristic causes air pollutants to be trapped and accumulated within the basin, where urban areas  were located. In the issue of of sustainable city, rainwater could be potential sources of  fresh water. However, air pollution in urban area might alter the natural rainwater composition. Characterization of rainwater was  conducted by collecting rainwater bulk samples at 4 (four) sites located in a transect from high elevation to the lowest at the base of the Bandung basin. Identification of trace metals, cations and anions were performed in rainwater collected in Bandung City during rainy seasons in February to March 2016. Acidity (pH), conductivity, anions and cations (SO42-, NO3-, Cl-, Ca2+, Mg2+, Na+, K+ and NH4+) and trace metals of Ag, Al, As, Ba, Cd, Co, Cr, Cu, Fe, Ni, Pb, Sb, Se, Sn, Sr and Zn were analysed. During the sampling period,  the rainfall rate ranged between 19.02 mm/week to 130.48 mm/week. The results show that rainwater pH were 4.10 – 5.95. The dominant chemical composition of rainwater were sulfat (37% – 39%) and ammonium (17% - 26%), followed by nitrate. The trace metals analyses indicated that lead (Pb) had the highest concentration (mean = 76.68 µg/L). The concentration of the trace metals decreased in order of Pb, Fe, Zn, Al, Se, Cu, As, Ba, Co, Sr, Ni, Cd, Cr, Sn and Sb. Lead is a toxic compound, resulting from human activities, such as fossil fuel burning, mining and manufacturing. The initial analysis of rainwater composition including heavy metals suggested that rainwater contain various and potential harmful substances, including heavy metals. These findings are particularly important  and should be taken into consideration in the context of  rainwater as a water sources in urban area, e,g. rainwater harvesting for the domestic purposes and urban farming.
Modelling of Tropospheric Ozone Concentration in Urban Environment Wasi’ah, Nadiyatur Rahmatikal; Driejana, Driejana
IPTEK Journal of Proceedings Series No 6 (2017): The 3rd International Conference on Civil Engineering Research (ICCER) 2017
Publisher : Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j23546026.y2017i6.3279

Abstract

Tropospheric ozone is harmful to human health and plants. It is resulted from photochemical processes involving NOx and VOCs from reactions of motor vehicle emissions and solar radiation in polluted urban environment. Historical data in Jakarta indicated that ozone concentrations often exceeded ambient standard threshold.  To minimize its impact to human health it is important to predict its concentration. This paper reports the use of multivariate statistical method to predict ozone concentration, using precursor concentration and meteorological parameters.  CH4, CO, NMHC, NO, NO2, THCdata concentration, wind direction and speed, temperature, solar radiation and relative humidity during 2011 - 2012 were used to build the model. Multiple linear regressions were applied to predict ozone concentration at Thamrin Station, Jakarta. These data were used as predictors at time (t) to estimate the ozone concentration at time (t +1). Meteorological conditions were found to strongly affect the concentration of ozone. The strongest relationship was found between ozone and temperature (0.513, p = 0.000). Weaker but significant positive correlations were found for  solar radiation and NO2 (r = 0.242, p= 0.000),. NMHC and NO correlation (r= 0.353, p= 0.000).  Both NO and NMHC are freshly emitted from exhaust gas.  Correlations between humidity, wind speed and direction were negative. Methana, NMHC, were negatively correlated with ozone due to their roles for producing NO2 as the main precursor, while NO was for its scavenging reaction with O3. Based on Adjusted R2 value, all predictors could explain variation in ozone concentration of approximately 46.32%. These findings will be useful as input in urban transportation planning and management in cities with tropical climate like Indonesia, as all precursors are emitted from vehicle combustion.