Chakim, M Ghufron
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Mitigating Heavy Metal Contamination in Agricultural Soils with Biosilica-Humic Acid as Soil Amendment Strategies in Industrial Peripheries Chakim, M Ghufron; Mindari, Wanti; Sasongko, Purnomo Edi
Acta Solum Vol 3 No 3 (2025): Juli 2025
Publisher : Department of Soil, Faculty of Agriculture, Lambung Mangkurat University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/actasolum.v3i3.3367

Abstract

Soil contamination by heavy metals poses a significant threat to sustainable agriculture, especially in areas adjacent to industrial zones. This study demonstrates that while the initial application of the biosilica-humic acid (BSi-HA) soil amendment did not result in statistically significant changes in soil chemical properties within the first 7 days of incubation, prolonged incubation for 60 days revealed meaningful effects, particularly in reducing heavy metal availability in soil. Significant decreases in iron (Fe) and lead (Pb) concentrations were observed over time, with Fe reductions ranging from 45–67% and Pb reductions between 8–40%. These results are attributed to the synergistic effect of functional groups in BSi-HA—especially the carboxyl (–COOH) and hydroxyl (–OH) groups in humic acid—which exhibit high metal-binding affinity under acidic conditions (pH ~5). Although soil fertility parameters such as C-organic content and cation exchange capacity (CEC) showed a declining trend due to microbial activity during incubation, the ability of BSi-HA to immobilize heavy metals without exceeding safe thresholds highlights its potential as a sustainable soil amendment. Moreover, previous findings indicating reductions of up to 90% for Pb and 76% for Cd in plant tissues further support the efficacy of BSi-HA in mitigating heavy metal contamination in agricultural soils near industrial zones. Further long-term studies are recommended to evaluate BSi-HA's remediation capacity, persistence, and impact on crop yield and food safety. Combining biosilica and humic acid offers a promising, eco-friendly approach for managing heavy metal contamination in soils.
Humic Silica for Optimising Soil Phosphorus Availability and Phosphorus Uptake by Maize Plants on Industrial Contaminated Lands Aditama, Diqy Ridwan; Mindari, Wanti; Maroeto, Maroeto; Chakim, M Ghufron
Jurnal Teknik Pertanian Lampung (Journal of Agricultural Engineering) Vol. 14 No. 5 (2025): October 2025
Publisher : The University of Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/jtepl.v14i5.1748-1757

Abstract

This study aimed to evaluate the effect of humic-silica application on P availability and P uptake by corn in land contaminated with heavy metals. The experiment was arranged in a Completely Randomized Design (CRD) with two treatment factors. The first factor consisted of three industrial locations: the pharmaceutical industry, the animal feed industry, and the paper industry. The second factor consisted of four levels of humic-silica application (in kg/ha): 0, 10, 20, and 30. Observations were made at the age of 14 and 70 days after planting (DAP). The parameters included soil organic carbon, Cation Exchange Capacity (CEC), soil P-available, and total P uptake by corn plants. Results showed that the humic-silica application at 20 kg/ha had a significant effect on P-available and P uptake by corn plants. This positive effect was consistent in the three industrial locations, both in 14 DAP and 70 DAP observations. These findings indicate that the use of humic-silica at 20 kg/ha has potential to reduce the negative impacts of heavy metal pollution on the availability of plant nutrients in industrial lands. This study provides insight into strategies for managing industrially contaminated lands to increase agricultural productivity, especially in terms of increasing the availability and absorption of phosphorus by corn plants.