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All Journal Communications in Science and Technology Indonesian Journal of Material Research
Badri, Arini Fousty
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Chemical Engineering, Chemistry & Bioengineering Civil Engineering, Building, Construction & Architecture Electrical & Electronics Engineering Energy Engineering

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Journal : Indonesian Journal of Material Research

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Effectiveness of Modified ZnAl-LDH Developed with POM for Competitive Adsorption of Heavy Metals in Purification Systems Normah, Normah; Oktriyanti, Melantina; Badri, Arini Fousty
Indonesian Journal of Material Research Vol. 2 No. 3 (2024): November
Publisher : Magister Program of Material Science Graduate School of Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/ijmr.20242347

Abstract

This study investigates the effectiveness of ZnAl-LDH modified with polyoxometalate (POM) as an adsorbent material in the competitive adsorption of heavy metal ions Cr(VI) and Fe(II). The material was synthesized using the co-precipitation method, resulting in ZnAl-LDH@POM with enhanced interlayer spacing, a specific surface area 14 times more significant, and increased surface-active sites. Characterization using XRD, FT-IR, and BET confirmed the successful structural modification and improved adsorption properties. Kinetic studies revealed that adsorption followed a pseudo-second order kinetic model, achieving maximum efficiency within 50 minutes. Isothermal analysis demonstrated maximum adsorption capacities (???????????????? ) of 92.95 mg/g for Fe(II) and 44.44 mg/g for Cr(VI). These findings highlight the potential of ZnAl-LDH@POM as an effective adsorbent for treating heavy metal-contaminated wastewater.
Co-Authors Aldes Lesbani Mardiyanto Normah Normah, Normah Oktriyanti, Melantina Risfidian Mohadi Tarmizi Taher