Syarifudin, Abimanyu Putra
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High Thermal Stability Silica Nanofluids For EOR in Sandstone Reservoir Subagio, Agus; Rowi, Khasan; Ngadiwiyana; Taufiq, Heydar Ruffa; Azis, Muhammad Mufti; Prasetiyo, Bayu Dedi; Sitompul, Victor; Paryoto, Sumadi; Winata, Denie Tirta; Diharja, Tino; Yutaka, Michael Arya; Syarifudin, Abimanyu Putra; Firmansyah, Wahyu; Koestono, Hary
Scientific Contributions Oil and Gas Vol 49 No 1 (2026)
Publisher : Testing Center for Oil and Gas LEMIGAS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/scog.v49i1.2000

Abstract

The development of silica nanofluids for enhanced oil recovery (EOR) has gained significant attention. However,  their application is limited bypoor stability under high temperature, and high salinity conditions. Our previous studies demonstrated that using the anionic surfactant alpha olefin sulfonate (AOS) combined with the co surfactant disodium laurent sulfosuccinate (DLS) at consentrations of 0.3% AOS and 0.3% DLS significantly enhanced thermal stabilility, reduced IFT, decreased wettability, and increased incremental oil recovery. This study reports a one step synthesis method for preparing silica nanofluids using hydrophilic colloidal nano silica (CNS) stabilized with the AOS and DLS at surfactant concentrations above 0.3%. Nanofluids were formulated with formation water from a reservoir in Sumatra, Indonesia. We systematically evaluated the effects of AOS-DLS concentrations on the thermal stability, turbidity, interfacial tension (IFT), wettability, filtration test, and core flooding performance. The optimized formulation of stable silica nanofluids for EOR applications under reservoir relevant conditions was also systematically evaluated. The silica nanofluid (0.3% AOS + 0.3% DLS) exhibited more than 3 months of stability at 60 °C. It also had a low contact angle of 13.88 ͦ and a reduced IFT of 6.3x10-1 mN/m. The filtration ratio was 1.2. Spontaneous imbibition resulted in a recovery factor (RF) of 59%. Core flooding analysis yielded an incremental RF of 12.9% of the OOIP. These results demonstrate the synergistic role of silica nanoparticles and surfactants in improving nanofluid stability, reducing IFT, and enhancing oil recovery. This supports their potential application in chemical flooding for sandstone reservoirs.
Synergy of Nano Silica and Anionic Surfactant Fluid as Chemical Enhanced Oil Recovery Rowi, Khasan; Subagio, Agus; Ngadiwiyana; Taufiq, Heydar Ruffa; Azis, Muhammad Mufti; Prasetiyo, Bayu Dedi; Sitompul, Victor; Paryoto, Sumadi; Winata, Denie Tirta; Diharja, Tino; Yutaka, Michael Arya; Syarifudin, Abimanyu Putra; Firmansyah, Wahyu; Koestono, Hary
Scientific Contributions Oil and Gas Vol 48 No 4 (2025)
Publisher : Testing Center for Oil and Gas LEMIGAS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/scog.v48i4.1951

Abstract

Silica nanofluids attract significant attention for enhanced oil recovery (EOR) applications due to their ability to alter rock wettability. However, silica nanofluids exhibit limitations in thermal stability. The addition of anionic surfactants aims to overcome these limitations. The synergisticAnionic surfactants are added to address the thermal stability issues of silica nanofluids. The synergy interaction between silica nanoparticles (SNPs) and anionic surfactants enhances  wettability alteration, reduces interfacial tension (IFT), improves thermal stability, and increasing oil recovery. This study investigates the synergistic effects of SNPs, alpha olefin sulfonate (AOS) surfactant, and disodium laureth sulfosuccinate (DLS) co-surfactant in nanofluid formulations applied to sandstone reservoirs. Laboratory experiments employ colloidal nano silica with two particle sizes, 8 nm (SNP-01) and 3 nm (SNP-02), combined with AOS-DLS anionic surfactants at various concentrations . The study showed that the silica nanofluid remains stable for up to 3 months at temperatures below 80°C for both SNP types at a concentration of 0.1% with surfactant concentrations 0.3% AOS and 0.3% DLS in  3% brine solution. The addition of SNPs decreases the contact angle, whereas surfactants do not significantly affect the contact angle; however, surfactant effectively reduce the IFT, while  nano silica shows minimal influence on IFT values. Core flooding analysis showed that the SNP-02 nanofluid produced the highest recovery factor of 12.1% OOIP. Futhermore, SEM analysis showed that silica nanofluid injection removes surfactant impurities and enhances rock porosity.