Air pollution has become a global issue due to rapid urbanization and industrialization. Air quality monitoring is essential for mitigating the adverse effects of air pollution on public health and the environment. This study presents a solar-powered internet of thing (IoT)-based air quality monitoring system designed for autonomous operation in outdoor settings. The prototype integrates an ESP32 microcontroller with low-cost sensors for PM2.5, PM10, temperature, humidity, and heat index. Powered by a solar panel and battery, the system ensures off-grid functionality, while Wi-Fi transmission to the Blynk platform, enables real-time visualization, historical record storage, and instant user access through mobile dashboards. The system was calibrated against reference instruments and deployed for 14 consecutive days. Results confirmed stable data transmission and reliable performance that suitability for outdoor use without reliance on grid power under real-world conditions. Furthermore, correlation analysis showed a strong relationship between PM2.5 and PM10, and moderate associations with humidity. Regression analysis further identified humidity and heat index as the most significant predictors, while temperature exhibited only minor influence. These findings demonstrate the feasibility of a low-cost, portable, and energy-autonomous IoT monitoring system, providing accurate real-time insights to support evidence-based air quality management.