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Journal : Jurnal Kimia Terapan Indonesia

PENGARUH TEKNIK SINTESIS TERHADAP KUALITAS PRODUK FATTYAMINA SEKUNDER Komar Sutriah; Zainal Alim Mas'ud; Tun Tedja Irawadi
Jurnal Kimia Terapan Indonesia Vol 13, No 1 (2011)
Publisher : Research Center for Chemistry - LIPI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (5962.283 KB) | DOI: 10.14203/jkti.v13i1.123

Abstract

Secondary fattyamines has been synthesized by reacting primary fatty amines with acylchlorides and continued with reducing the corresponding secondary fattyamides formed to secondary fattyamines using LiAIH<I'Fatty amines are raw material of natural-based surfactants that can be derived from fatty acids, olefins, or alcohols, of which can be synthesized from natural sources such as palm oil. Conversion of secondary fatty amides to secondary fatty amines was evaluated through the quality of FTIR spectra on wave number of 1639-1645 em' (C=O vibration) and 1544-1555 em" (vibrations of C-H and of secondary amine N-H). Method of synthesis by using closed reflux syncore reactor was better than those of using microwave teflon tubes, and open reflux. The yield of 9 different secondary fatty amines obtainedfrom 5 to 27 replicates by the closed reflux syncore reactor method varied from 17%to 96%.Keywords: Natural-based surfactant, secondary fatty amines