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Kiky C. Sembiring
Research Center for Chemistry of Indonesian Institute of Sciences Kawasan Puspiptek, Serpong15314, Tangerang
Materials Science & Nanotechnology

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UNIQUE CONFORMATION OF RH(I) PILLAR COMPLEXES IMMOBILIZED ON TAENIOLITE Kiky C. Sembiring; Shogo Shimazu
Jurnal Sains Materi Indonesia VOL 13, NO 1: OKTOBER 2011
Publisher : Center for Science & Technology of Advanced Materials - National Nuclear Energy Agency

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (230.465 KB) | DOI: 10.17146/jusami.2011.13.1.5392

Abstract

UNIQUE CONFORMATION OF RH(I) PILLAR COMPLEXES IMMOBILIZED ON TAENIOLITE. Rhodiumpillar complex with chiral diamine ligands, Rh-Cn-(-)-CHDA, were synthesized and intercalated with various loading amounts in the range of 19 - 26%CEC, Cation Exchange Capacity (CEC) into Lithium Taeniolite (LiTN) These pillared catalysts (Rh-Cn-(-)-CHDA/TN) were characterized by XRD, elementary analysis, and FT-IR. Results of XRD analysis showed that the clearance space of the catalyst interlayer increased proportionally with the alkyl chain length of the ligandwith the slopeof 0.14 nm/CH2.
Co-Authors Shogo Shimazu