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Edi Priyo Utomo
Chemistry Department Faculty of Science Brawijaya University
Chemical Engineering, Chemistry & Bioengineering Chemistry Materials Science & Nanotechnology Medicine & Pharmacology

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Hydrogenation/Deoxygenation (H/D) Reaction of Furfural-Acetone Condensation Product using Ni/Al2O3-ZrO2 Catalyst Adam Mahfud; Siti Mariyah Ulfa; Edi Priyo Utomo
The Journal of Pure and Applied Chemistry Research Vol 5, No 2 (2016)
Publisher : Chemistry Department, The University of Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (814.928 KB) | DOI: 10.21776/ub.jpacr.2016.005.02.263

Abstract

The catalytic hydrogenation/deoxygenation (H/D) reaction was carried out using Ni/Al2O3-ZrO2 catalyst. The 10% (wt/wt) of Ni were impregnated on Al2O3-ZrO2 (10NiAZ) by wet impregnation method followed by calcination and reduction. X-Ray diffraction analysis showed that Nideposited on the surface, with specific surface areas (SBET) was 48.616 m2/g. Catalyst performance were evaluated for H/D reaction over furfural-acetone condensation products, mixture of 2-(4-furyl)-3-buten-2-on and 1,5-bis-(furan-2-yl)-pentan-3-one. The reaction was carried out in a batch, performed at 150°C for 8 hours. The H/D reaction gave alkane derivatives C8 and C10 by hydrogenation process followed by ring opening of furan in 15.2% yield. While, oxygenated product C10-C13 were also detected in 17.2% yield. The increasing of pore volume of 10NiAZ might enhance catalyst activity over H/D reaction. The alkene C=C bond was easy to hydrogenated under this condition by the lower bond energy gap.
Co-Authors Adam Mahfud Siti Mariyah Ulfa