Agung Imaduddin
Pusat Penelitian Metalurgi dan Material – LIPI

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Effect of Sintering Time on Superconducting Wire Bi-Pb-Sr-Ca-Cu-O With Dopant MgO Sheated Ag Using Powder in Tube Method Hariyati Lubis; Agung Imaduddin; Eddy Marlianto; Pius Sebleku; Eidi Sihombing
Journal of Aceh Physics Society Volume 7 Number 1, January 2018
Publisher : PSI-Aceh

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Abstract

Telah dilakukan penelitian mengenai variasi waktu proses sintering pada kawat superkonduktor Bi-Pb-Sr-Ca-Cu-O dopan MgO dengan selubung Ag. Bahan-bahan yang digunakan ialah Bismuth (III) Oksida, Timbal (IV) Oksida, Strontium Carbonate, Calcium Carbonate, Copper (II) Oksida dan Magnesium Oksida dengan tingkat kemurnian tinggi. Proses sintering dalam furnance dilakukan pada suhu konstan selama 30 jam dan 9 jam lalu didinginkan dalam tungku. Hasil karakterisasi X-Ray Diffraction dan search match v1.10, sampel kawat superkonduktor monofilamen Bi1.6Pb0.4Sr2Ca2Cu3O10+δ dan Bi1,6Pb0,4Ca1,95Mg0,05Cu3O10+δ dengan variasi waktu sintering masing-masing 30 jam dan 9 jam memiliki nilai intensitas sebesar 993,77cts dan 902,86 cts. Penambahan waktu sintering pada sampel superkonduktor mengakibatkan penurunan fraksi volume 2223 dengan masing-masing nilai fraksi volume sebesar 60% dan 59%, hal ini menunjukkan adanya impuritas berupa senyawa CuO. Parameter kisi diperoleh yaitu Orthorhombic dengan a=5,347 Å, b=5,416 Å dan c=30,67 Å. Hasil morfologi SEM menunjukkan permukaan homogenitas butir sampel terlihat cukup baik, dan terdistribusi secara acak. Pada sampel kawat superkonduktor monofilamen Bi1.6Pb0.4Sr2Ca1.95Mg0.05Cu3O10+δ dengan waktu sintering 30 jam menunjukkan Tconset=72 K dan Tczero=33 K. Sampel kawat superkonduktor monofilamen Bi1.6Pb0.4Sr2Ca1.95Mg0.05Cu3O10+δ dengan waktu sintering 9 jam menunjukkan Tconset=78 K dan Tczero=58 K. Variation of sintering time has been done in Bi-Pb-Sr-Ca-Cu-O superconducting wires dopant MgO using Ag-sheathed. The samples were prepared using highly pure powders of Bismuth (III) Oxide, Lead (IV) Oxide, Strontium Carbonate, Calcium Carbonate, Copper (II) Oxide and Magnesium Oxide. Sintered at a constant temperature for 30 h and 9 h then cooled in the furnace. The structure of the samples was studied by X-Ray Diffraction and search match v1.10. XRD patterns of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ and Bi1,6Pb0,4Ca1,95Mg0,05Cu3O10+δ monofilament superconducting wires using variation of sintering time for 30 h and 9 h have intensity values of 993.77cts and 902.86 cts. The addition of sintering time to superconductor samples resulted decrease in the volume fraction of 2223 with each volume fraction value of 60% and 59% indicating of impurity phases present CuO compounds. The Orthorhombic structure with the lattice constants are calculated as a = 5,347 Å, b = 5,416 Å, and c = 30,67 Å. The surface morphology studied by SEM, show that surface homogeneity, each grain grows in random directions. For the prepared Bi1,6Pb0,4Ca1,95Mg0,05Cu3O10+δ monofilament superconducting wires sample with 30 h, the onset Tc is at 72 K and the resistivity drops to zero at 33 K. Sample of Bi1.6Pb0.4Sr2Ca1.95Mg0.05Cu3O10+δ δ monofilament superconducting wires with 9 h, the onset Tc is at 78 K and the resistivity drops to zero at 58 K. Keywords : BPSCCO superconducting wire, Sheated Ag, Dopant MgO, Sintering time DAFTAR PUSTAKAAbbas M.M., Abass L.K and Salman U., (2012), Influences of Sintering Time on the Tc of Bi2-xCuxPb0.3Sr2Ca2Cu3010+ High Temperature Superconductors, Energy Procedia 18, 215-224 Abbas, M.M., Abbas, L.K., Bahedh, H.S. 2015. Superconducting Properties of Bi2-SbxPb0,3Sr1,9Ba0,1Ca2Cu3O10+δ Compounds. Journal of Applied Science Research. 11. 22: 164-172Darsono, N., Imaduddin, A., Raju, K., Yoon, D.H., (2015), Synthesis and Characterization of Bi1.6Pb0.4Sr2Ca2Cu3O7 Superconducting Oxide by High-Energy Milling, J Supercond Nov Magn.E. Chew,. (2010), Superconducting Transformer Design And Construction, University of Canterbury, Christchurch, New Zealand. MarchHamadneh, I., Halim, S. A., dan Lee, C. K., (2006),  Characterization of Bi1.6Pb0.4Sr2Ca2Cu3Oy Ceramic Superconductor Prepared Via Coprecipitation Method at Different Sintering Time, J. Mater. Sci, 41: 5526-5530.Hermiz G.Y., Aljurani B.A., Beayaty M.A., (2014), Effect of Mn Substitution on the Superconducting Properties of Bi1.7Pb0,3Sr2Ca2-xMnxCu3O10+, International Journal Of Engineering and Advanced Technology (IJEAT). 3. 4: 213-217John R Hull, (2003), Applications of high-temperature superconductors in power technology, Reports on Progress in Physics, Volume 66, Number 11Lu, X.Y., Yi, D., Chen, H., Nagata, A. 2016. Effect of Sn, MgO and Ag2O mix-doping on the formation and superconducting properties of Bi-2223 Ag/tapes. Physics Procedia. 81: 129-132Meretliev Sh., Sadykov K.B., Berkeliev A., (2000), Doping of High Temperature Superconductors, Turk J Phy.24: 39-48Mohammed, N. H., Ramadhan A., Ali I. A., Ibrahim, I. H., dan Hassan, M. S, (2012), Optimizing the Preparation Conditions of Bi-2223 Superconducting Phase Using PbO and PbO2, Materials Sciences and Applications, 3: 224-233.Roumie, M., Marhaba, S., Awad R., Kork M., Hassan I., Mawassi R., (2014), Effect of Fe2O3 Nano-Oxide Addition on the Superconducting Properties of the (Bi,Pb)-2223 Phase, Journal of Supercond Nov Magn, 27: 143-153Serkan, A., (2008), Production of YBCO Superconductor Sample by Powder-In-Tube Method (PITM); and Effect of Cd and Ga Doping on the System, University, Department of Physics, Malatya-TurkeySharma, D., Kumar, R., Awana, V.P.S. 2013. DC and AC Susceptibility Study of Sol-Gel Synthesized Bi2Sr2CaCu2O8+x Superconductor. Ceramic International. 39:1143-1152
Studi Awal Sintesis dan Karakterisasi Bi(Pb)-Sr-Ca-Cu-O dengan Penambahan Carbon Nanotube dan TiO2 Menggunakan Metoda Reaksi Padatan dan Proses Sintering Berulang [Preliminary Study Synthesis and Characterization of Bi(Pb)-Sr-Ca-Cu-O By Addition of Carbon Nanotube and TiO2 Using Solid Reaction Method and Recurrent Sintering Process] Rizki Syahfina; Bintoro Siswayanti; Sigit Dwi Yudanto; Agung Imaduddin; Nurul Suhada; Fauzan Amri; Mukti Hamjah Harahap
Metalurgi Vol 32, No 3 (2017): Metalurgi Vol. 32 No. 3 Desember 2017
Publisher : National Research and Innovation Agency (BRIN)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (571.06 KB) | DOI: 10.14203/metalurgi.v32i3.330

Abstract

Bi1.6Pb0.4Sr2Ca2Cu3O10+δ with the addition of carbon nanotubes (CNT) and TiO2 have been synthesized using solid state reaction method with the repeated sintering process. 0.1 wt % of CNT and 5 wt% of TiO2 have been added to analyze the effect on the synthesizing of 2223 phases. The samples were analyzed using XRD (X-ray diffractometer) and SEM (Scanning Electron Microscopy). Based on the XRD results, 2223 and 2212 were formed. The addition of CNTs and TiO2 reduced the intensity of 2223 phases. This is due to the addition of CNTs and TiO2 as an impurity and prevent the formation of the phases. Also, the repeated sintering process led to the increase of 2223 phase, and the decrease of 2212 phase. However, the repeated sintering process in the B-CNT and B-TiO samples eliminates the impurities phase thus increasing the volume fraction 2223 and decreasing the volume fraction 2212. Based on morphological structure through SEM observation, the addition of CNT in the Bi(Pb)-2223 samples formed longer plates with large porosity spaces while the addition of TiO2 formed clumps on the Bi(Pb)-2223 morphological structure. However, the repeated sintering process improves the morphological structure of B-CNT and B-TiO becomes increasingly denser and the smaller porosity space.AbstrakTelah dilakukan sintesis Bi1,6Pb0,4Sr2Ca2Cu3O10+δ dengan penambahan CNT (carbon nanotube) dan penambahan TiO2 menggunakan metode reaksi padatan dengan proses sintering berulang. Penambahan CNT sebesar 0,1 %berat dan TiO2 sebesar 5 %berat dan sintering berulang dilakukan untuk mempelajari pengaruhnya terhadap pembentukan fasa 2223 beserta pengotornya, dan mempelajari perubahan morfologi Bi1,6Pb0,4Sr2Ca2Cu3O10+δ. Bi1,6Pb0,4Sr2Ca2Cu3O10+δ yang dibuat dianalisis dengan XRD (x-ray diffractometer) dan SEM (scanning electron microscopy). Berdasarkan hasil XRD, penambahan 0,1 %berat CNT dan TiO2 sebesar 5 %berat pada superkonduktor Bi(Pb)-2223 diketahui menghasilkan fasa 2223, fasa 2212, dan juga fasa pengotor. Namun proses sintering berulang mampu mengurangi fasa impuritas, meningkatkan fraksi volume 2223, serta menurunkan fraksi volume 2212.   Berdasarkan pengamatan struktur morfologi melalui SEM, penambahan CNT pada superkonduktor Bi(Pb)-2223 membentuk serpihan memanjang dengan ruang porositas yang besar sedangkan penambahan TiO2 membentuk gumpalan pada struktur morfologi Bi(Pb)-2223. Proses sintering berulang mampu memperbaiki struktur morfologi B-CNT dan B-TiO menjadi semakin rapat dan ruang porositas yang semakin kecil.