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All Journal Reaktor Equilibrium Journal of Chemical Engineering
Paryanto Paryanto
Sebelas Maret University
Chemical Engineering, Chemistry & Bioengineering Chemistry Control & Systems Engineering Energy Engineering Materials Science & Nanotechnology

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Hydrogen Sulfide Removal from Biogas Using Digester Effluent Absorbent in a Continuous Vertical Column Sunu Herwi Pranolo; Paryanto Paryanto; Margono Margono; Bachtiar Rizaldy; Hendrix Yansah
Reaktor Volume 18 No. 3 September 2018
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (749.467 KB) | DOI: 10.14710/reaktor.18.03.160-165

Abstract

HYDROGEN SULFIDE REMOVAL FROM BIOGAS USING DIGESTER EFFLUENT ABSORBENT IN A CONTINUOUS VERTICAL COLUMN. Gas-Liquid mass transfer is one of the most commonly used phenomena in the chemical process, such as absorbtion. This research evaluates the value of liquid phase mass transfer coefficient of hydrogen sulfide removal from biogas in a continous contactor column for digester effluent-biogas system. This study was carried out by contacting biogas at certain flow with digester effluent continously in a counter-current flow packed bed column. Samples were taken in steady state condition. This research used raschig rings, large balls, and small balls as packing materials with surface areas are 0.9269 m2/m3, 0.6279 m2/m3, and 0.2992 m2/m3 respectively at volumetric flow rates of biogas from 0.1109 m3/h to 0.8846 m3/h. The results show that the relationship between the variables and mass transfer coefficient gives following mathematical model This model is valid in the range of (As·dt) and (Vg/dt·DL) respectively from 0.03 to 0.09 and from 237,267.08 to 3,307,522.67. Average error is 17.85%.
Characterization and Combustion Kinetics of Binderless and Bindered Dry Cow Dung Bio-Pellets Wusana Agung Wibowo; Ari Diana Susanti; Paryanto Paryanto
Equilibrium Journal of Chemical Engineering Vol 8, No 1 (2024): Volume 8, No 1 July 2024
Publisher : Program studi Teknik Kimia UNS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/equilibrium.v8i1.83645

Abstract

The effect of molasses addition as a binder in the manufacturing of cow dung bio-pellets on their characteristics and combustion kinetics have been studied. The bio-pellets characterization included the physical and mechanical properties as well as the proximate analysis and calorific values. Thermogravimetric analysis (TGA) was carried out using a macro-TGA apparatus under a non-isothermal conditions and an oxidative atmosphere to study the thermal decomposition characteristics. Then, the first order Coast and Redfern method was used to determined the kinetic parameters of bio-pellets combustion. It was found that the ash content of bio-pellets were tended to decreased, while the volatile matter and fixed carbon were tended to increase with the addition of molasses. Nevertheless, the density, the axial compressive strength and the calorific values of bindered bio-pellets were decreased due to the higher amounts of water in the raw mixtures. Thermogravimetric analysis provided an information that the combustions of cow dung bio-pellets took place in three stages of decompositions The bindered bio-pellet began to decompose at lower temperatures than the binderless bio-pellet with a higher weight loss percentage. According to the comprehensive combustion characteristic index (S), the combustion performance of both binderless and bindered bio-pellets were similar. The addition of molasses as a binder tended to reduce the ignition temperature and activation energy for all stages of bio-pellets combustion. Keywords:Bio-pellet, Characterization, Cow Dung, Combustion Kinetics, Molasses
Co-Authors Ari Diana Susanti Bachtiar Rizaldy Hendrix Yansah Margono Margono Sunu Herwi Pranolo Wusana Agung Wibowo