Neneng Laksminingpuri Sanusi
Pusat APlikasi Isotop dan Radiasi-BATAN

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Penentuan Komposisi Bahan Bakar Nabati Dalam Bahan Bakar Minyak Campuran Menggunakan Metode Direct Counting C-14 Neneng Laksminingpuri Sanusi; Moch Faizal Ramadhani; Nurfadhlini Nurfadhlini; Lies Aisyah
EKSPLORIUM Vol 42, No 2 (2021): November 2021
Publisher : Pusat Teknologi Bahan Galian Nuklir - BATAN

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17146/eksplorium.2021.42.2.6363

Abstract

ABSTRAK. Telah dilakukan penentuan komposisi bahan bakar nabati (BBN) dalam bahan bakar minyak campuran (BBMC) dengan metode direct counting C-14. Penentuan komposisi BBN dalam BBMC dilakukan dengan cara memipet 10 mL BBMC ke dalam vial gelas kemudian ditambahkan 10 mL larutan sintilator Ultima Gold F (UGF) ke dalamnya. Vial tersebut dikocok agar campuran menjadi homogen kemudian dicacah menggunakan LSC (Liquid Scintillation Counter) Elmer Perkin 2900TR selama 20 menit sebanyak 30 siklus. Hasil pencacahan ditampilkan dalam bentuk tSIE (transformed external standard spectrum) dan cpm (cacahan permenit). Hasil analisis memperlihatkan nilai cpm yang meningkat seiring kenaikan persentase BBN dalam BBMC. Nilai cpm terendah dan tertinggi untuk sampel bensin, avtur, dan solar berturut-turut adalah 14,2363 dan 62,0343, 10,664 dan 44,535, serta 9,410 dan 61,789. Terdapat korelasi kuat antara nilai tSIE dan nilai cpm pada bensin dan solar tapi tidak pada avtur. Hasil analisis terhadap sampel uji menunjukkan bahwa sampel tersebut berada di luar grafik deret sampel. Metode direct counting ini diharapkan dapat menjadi referensi dalam uji mutu BBMC.ABSTRACT. The composition of biofuel (BF) in mixed oil fuel (MOF) has been determined using the C-14 direct counting method. Determination of the composition of BF in MOF was carried out by pipetting 10 mL of BBMC into a glass vial and then adding 10 mL of Ultima Gold F (UGF) scintillator solution into it. The vial was shaken so that the mixture became homogeneous and then counted using the Elmer Perkin 2900TR LSC (Liquid Scintillation Counter) for 20 minutes for 30 cycles. The results of the counting are displayed in the form of tSIE (transformed external standard spectrum) and cpm (counts per minute). The results of the analysis show that the value of cpm increases with the increase in the percentage of BF in MOF. The lowest and highest cpm values for gasoline, avtur, and diesel samples were 14.2363 and 62.0343, 10.664 and 44.535, and 9.410 and 61.789, respectively. There is a strong correlation between tSIE and cpm values for gasoline and diesel but not for avtur. The results of the analysis of the test sample indicate that the sample is outside the sample series graph. This direct counting method is expected to be a reference in the BBMC quality test.
Studi Karakteristik Air-Tanah di Kawasan Nuklir Pasar Jumat (KNPJ) dengan Metode Hidrokimia dan Isotop Alam Neneng Laksminingpuri Sanusi; Nurfadhlini Nurfadhlini; Satrio Satrio
EKSPLORIUM Vol 39, No 1 (2018): Mei 2018
Publisher : Pusat Teknologi Bahan Galian Nuklir - BATAN

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (731.626 KB) | DOI: 10.17146/eksplorium.2018.39.1.4100

Abstract

Telah dilakukan penelitian air-tanah di Kawasan Nuklir Pasar Jumat (KNPJ) menggunakan metode hidrokimia dan isotop alam. Penelitian dilakukan dengan mengambil sejumlah sampel air di beberapa kawasan KNPJ dan sekitarnya. Sampel air tersebut kemudian dianalisis konsentrasi kimia airnya (anion-kation) dan konsentrasi isotop alam d2H dan d18O menggunakan alat lasser counter. Analisis kimia air dilakukan menggunakan metode ion kromatografi dan titrasi. Tujuan penelitian ini, yaitu untuk mengetahui karakteristik air-tanah terhadap kemungkinan interaksi dengan air permukaan sekitarnya. Berdasarkan hasil analisis hidrokimia (anion-kation) dan isotop alam (d2H, d18O) menunjukkan bahwa air-tanah dalam masih mencerminkan karakter sebagai air-tanah segar atau freshwater. Air-tanah akuifer dalam juga terindikasi tidak berhubungan dengan air-tanah akuifer dangkal yang berada di atasnya. Air-tanah dangkal, sebagian besar masih menunjukkan karakter air-tanah segar dan sebagian lainnya, yaitu SB-8, SB-9, dan SB-10, air-tanahnya mengalami pertukaran ion dan interaksi dengan air permukaan. Air permukaan untuk SB-8 diperkirakan berasal dari rembesan larutan pupuk tanaman sedangkan untuk SB-9 dan SB-10 air permukaan diperkirakan berasal dari rembesan tanki kotoran (septic tank). Groundwater research has been conducted in Nuclear Area of Pasar Jumat (KNPJ) using hydrochemical data and natural isotopes methods. The research was conducted by taking a number of water samples in some areas of KNPJ and also its surrounding areas. The water samples were then analyzed its hydrochemical concentration (anion-cation) and natural isotope concentration d2H and d18O using lasser counter device. Water chemical analysis was conducted by using ion chromatography and titration methods. The purpose of this research is to know the characteristics of groundwater to the possibility of its interaction with the surrounding surface water. Based on the results of hydrochemical analysis (anion-cation) and natural isotopes (d2H, d18O) indicates that groundwater still reflects the character as fresh groundwater or freshwater. The deep aquifer groundwater is also indicated to be unrelated to groundwater of shallow aquifers located above it. While most shallow groundwater still show the character of fresh groundwater, and some others namely SB-8, SB-9, and SB-10, the groundwater undergo ion exchanges and interact with surface water. Surface water for SB-8 is estimated come from the seepage of the liquid plant fertilizer, whereas for SB-9 and SB-10 surface water is estimated come from septic tank seepage.