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Waste-Cooking-Oil Free Fatty Acid Reduction Using Deep Eutectic Solvent as Raw Material of Biodiesel Mutiara Putri; Aida Syarif; Leila Kalsum
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 6, No 2 (2021): June 2021
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v6.i2.40

Abstract

The purpose of this study was to extract the free fatty acid (FFA) of waste-cooking-oil through liquid-to-liquid extraction using choline chloride as a raw material for Deep Eutectic Solvent (DES) as a waste-cooking-oil purifier. Waste-cooking-oil is obtained from the waste of a fast food factory located in Sukarame, South Sumatera. Making a Dep Eutectic Solvent (DES) using compounds of ethylene glycol as Hydrogen Bond Donor mixed with a choline chloride Hydrogen Bond Acceptor with five molar ratios, a reaction temperature of 60 °C and a stirring speed of 150 rpm and 200 rpm for 90 minutes. The extraction molar ratio of waste-cooking-oil and DES with four ratios of molar ratios, extraction time of 2 hours at 60 °C and retention time of separation between DES and used cooking oil was 24 hours. The decrease in FFA of waste-cooking-oil was the highest at 83.87% in the DES 2. Its proves that DES is able to purify waste-cooking-oil by extraction methods to reduce FFA and adsorb other materials
Biogas Purification by Adsorption Method Using Activated Carbon and Zeolite Adsorbents Fitrah Fourqoniah; Leila Kalsum; Selastia Yulianti
Equilibrium Journal of Chemical Engineering Vol 7, No 2 (2023): Volume 7, No 2 December 2023
Publisher : Program studi Teknik Kimia UNS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/equilibrium.v7i2.77835

Abstract

Abstract. Biogas is an alternative energy that is formed from the fermentation of organic matter in gaseous form. Biogas consists of several gas mixtures with the main components methane (CH4) and carbon dioxide (CO2) with a small amount of steam. Biogas is an alternative technology that produces environmentally friendly, cheap and renewable fuel because it comes from biomass, organic liquid waste, food scraps, organic waste, leaves and animal manure resulting from the fermentation process. This study aims to purify biogas by adsorption method using activated carbon and zeolite adsorbents to obtain optimal methane gas by varying the biogas flow rate and the amount of adsorbent composition. Variation in the ratio of the amount of adsorbent (activated carbon: zeolite) is 0%:100%, 30%:70%, 50%:50%, 70%:30%, 100%:0% and the flow rate variation used is 0.2 liter/minute, 0.4 liter/minute, and 0.6 liter/minute. From the purification results, an analysis of the gas content contained in the biogas was carried out using a gas analyzer. The results showed that the best flow rate was the smallest flow rate, which was 0.2 liter/minute, and the best variation in the amount of adsorbent was 0%:100% adsorbent (activated carbon: zeolite) with 81.40% methane content.Keywords:Biogas, Activated Carbon, Zeolite, Adsorption, Purification,