Valentina Matveeva Valentina Matveeva
Department of Biotechnology and Chemistry, Tver State Technical University, Afanasiy Nikitin str., 22, Tver 170026

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Kinetic Study of the Catalytic Pyrolysis of Oil-Containing Waste Kirill Chalov; Yury Lugovoy; Yury Kosivtsov; Mikhail Sulman; Esther Sulman; Valentina Matveeva Valentina Matveeva; Antonina Stepacheva
Bulletin of Chemical Reaction Engineering & Catalysis 2016: BCREC Volume 11 Issue 3 Year 2016 (December 2016)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (903.382 KB) | DOI: 10.9767/bcrec.11.3.572.330-338

Abstract

Basing on the experimental data the optimal parameters of the pyrolysis of heavy and residual hydrocarbons of oil were defined as follows: temperature of 500 °С; catalyst  of CoCl2 with the catalyst loading 5% (wt.) of the substrate weight. Under the optimal conditions the kinetic investigation of the pyrolysis process was carried out using the thermogravimetric method. According to the investigation, it was found that the activation energy of the catalytic pyrolysis of oil-containing waste decreased by 20-30 kJ/mol in comparison to non-catalytic process.