Bambang Rusdiarso
Departemen Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Gadjah Mada

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The Study of pH and Ionic Strength on Ni(II) and Pb(II) sorption using Humic Acid-Urea Formaldehyde (AHUF) Meidita Kemala Sari; Bambang Rusdiarso
Indonesian Journal of Chemical Science and Technology (IJCST) Vol 5, No 1 (2022): JANUARI 2022
Publisher : Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24114/ijcst.v5i1.33144

Abstract

The study of pH and ionic strength on Pb(II) and Ni(II) sorption with AHUF adsorbent has been investigated. The AHUF was synthesized from humic acid (AH) with urea-formaldehyde (UF) and characterization by FTIR, SEM-EDX, total acidity content, and pH zero point charge (pHpzc). The study of pH and ionic strength using the batch system. The formation of AHUF was identified based on; decreases in total acidity (349.30 cmol/kg), emerging peaks at 3351, 1258, and 1049 cm-1 by FTIR, and increases of N atoms 21.06% by EDX. The results indicate the adsorption of Pb(II) and Ni(II) are strongly dependent on pH and ionic strength at pH < 6. The AHUF have a pHpzc value is 4.82 with optimum sorption on pH 5. The variations of NaCl to adsorption Pb(II) and Ni(II) caused a decrease in the value of ionic activity from 0.999 M – 0.309 M, the amount of adsorbed will decreased.