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Spectrophotometric method for hg(ii) determination in aqueous environment using zinc-dithizonate complex Musa Ahmad Ahmad,; Elya Sufliza Marsom; Harun Hamzah
ASEAN Journal on Science and Technology for Development Vol. 18 No. 1 (2001): ASEAN Journal on Science and Technology for Development (AJSTD)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (593.32 KB) | DOI: 10.29037/ajstd.194

Abstract

This article described the use of zinc-dithizonate for spectrophotometric  determination of Hg(II) in aqueous environment. Zinc dithizonate was found to react selectively with Hg(II) to give a reddish yellow complex  with  optimum  absorbance  at  pH  1.0. This complex was found to be useful for  spectrophotometric determination of aqueous Hg(II) in the concentration range of 1.0 - 12.0 ppm. This method was also found to be reproducible with calculated relative standard deviation, RSD of 1.08%. At 1:1 mole ratio, interfering ions such as CH COO·, Pb2+ and Ag+ were found to interfere at degree 3 of interference of more than 10.0%.