Iqmal Tahir
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta 55281

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Computer Aided Design of Molecular Imprinted Polymer for Selective Recognition of Capsaicin Iqmal Tahir; Karna Wijaya; Shafiqul Islam; Mohd Noor Ahmad
Indonesian Journal of Chemistry Vol 14, No 1 (2014)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (259.762 KB) | DOI: 10.22146/ijc.21272

Abstract

Searching capsaicin-like molecule as an alternative dummy template has been conducted for the synthesis of Molecularly Imprinted Polymer (MIP) of capsaicin. Dummy template should be applied because synthesis of capsaicin practically has a problem due to its structure containing double bond at the aliphatic chains. Virtual searching was done using an online chemical database of ChemDB containing 5 million commercial molecules. Capsaicin structure was converted into SMILES code and then it was run on ChemDB with molecular similarity threshold of 0.5. There were 69 chemical structures obtained as the output and pseudocapsaicin was practically selected as the dummy template. Experimental result from the prediction evaluation showed that the use of capsaicin as template and pseudocapsaicin as dummy template produced MIPs that have separation factor of 1.28 and 1.25 respectively. It is suggested to choose pseudocapsaicin as dummy template for the synthesis MIP of capsaicin instead of using capsaicin molecule.
EFFECT OF MALEIC ANHYDRIDE POLYPROPYLENE ON THE PROPERTIES OF COCONUT SHELL FILLED THERMOPLASTIC ELASTOMERIC OLEFIN COMPOSITES Z.H. Tengku Faisal; Faisal Amri; Iqmal Tahir
Indonesian Journal of Chemistry Vol 10, No 2 (2010)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (369.532 KB) | DOI: 10.22146/ijc.21453

Abstract

Coconut shell (CS) is one of agro-waste material which has high natural lignocellulosics content. This material provides a potential resource as a reinforcement agent in thermoplastic elastomeric olefin (TEO). In this study, CS was used as filler in TEO composites. The effect of CS loading and Maleic Anhydride Polypropylene (MAPP) as compatibilizer on mechanical properties, morphology and thermal properties were studied. Results show that the increasing of CS loading has increased the tensile strength, elongation at break and Young's modulus of TEO/CS composites. At similar content, the effect of PP-g-MA as compatibilizer has improved the tensile strength, elongation at break and Young's modulus of TEO/CS composites. The SEM study of the tensile fracture surface of compatibilized composites indicates that the presence of PP-g-MA increased the interfacial interaction. TGA results show that the composites with addition of MAPP as a compatibilizer has better the thermal stability compared to composites without addition of MAPP at 600 °C. DSC analysis showed that the addition of MAPP decreases the crystallinity of TEO/CS composites. It was found that the presence of MAPP will extended the molecular chain of the TEO/CS composites.