E. Ristin Pujiindiyati
Center for the Application of Isotopes and Radiation Technology, National Nuclear Energy Agency, Jln. Cinere Pasar Jum’at PO.Box 7002 JKSKL, Jakarta 12070

Published : 2 Documents Claim Missing Document
Claim Missing Document
Check
Articles

Found 2 Documents
Search

INVESTIGATION OF STABLE ISOTOPE OF 18O AND 2H IN SHALLOW GROUNDWATER FROM KARAWANG AREA E. Ristin Pujiindiyati
Indonesian Journal of Chemistry Vol 8, No 2 (2008)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (285.228 KB) | DOI: 10.22146/ijc.21614

Abstract

Karawang area is well known as an agriculture area and 2% area is utilized for industries. Clean water demands increase due to developing industry development and population increasement. The origin of groundwater is necessary to keep the sustainability of water resources in this area. Stable isotopes such as 18O and 2H can be used as a parameter to trace the ground water origin. The methods used were Epstein-Mayeda and Zinc reduction for analysis 18O and 2H, respectively. Sampling period was conducted in major dry season in year 2002. The result showed that evaporation effect had influenced to the content of both isotopes in its shallow groundwater that caused a slope shift from its local meteoric line. The origin of its shallow groundwater was from rainwater infiltrating directly in less than 10 m altitude. Citarum River showed more depleted values in both isotopes compared to shallow groundwater and it indicated that its water might originate from spring at the altitude of 600 m.
INVESTIGATION OF DISSOLVED SULPHATE IN VARIOUS GEOTHERMAL FIELDS OF SUMATRA USING OXYGEN AND SULPHUR ISOTOPES E. Ristin Pujiindiyati; Zainal Abidin
Indonesian Journal of Chemistry Vol 6, No 2 (2006)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (270.027 KB) | DOI: 10.22146/ijc.21756

Abstract

There are at least 30 high temperature systems; eleven active volcanoes, five degassing volcanoes and one caldera volcano controlled by Sumatra Fault Zone over a length of 1700 km. To understand this geothermal field system, some information about geochemistry including isotope composition in its fluid is needed. Sulphur-34 and oxygen-18 isotopes in dissolved sulphate pair have been used to determine the origin of acidic fluid of sulphate and to evaluate the process involved. The fluids from eight hot springs, two fumaroles, four deep wells and crater have been collected in along Sumatra geothermal fields. Sulphur-34 (d 34S (SO4), 0/00 CDT) and oxygen-18 (d 18O (SO4), 0/00 SMOW) in sulphate is analyzed according to Robinson-Kusakabe and Rafter method, respectively. The d 34S (SO4) values from Sibayak wells are more enriched of 16.8 0/00 to 18.2 0/0 that may indicate the dissolution of anhydrite minerals or isotope partitioning in hydration of SO2. The d 34S (SO4) values from two fumaroles (Pusuk Bukit - North Sumatra and Rantau Dadap - South Sumatra) are at depleted value of -0.150/00 and 1.80/00, those are close to d 34S from magmatic sulphur.  In general, the d 34S (SO4) of springs spread in a wide range of 5.250/00 to14.20/00 and show a mixing process between atmospheric sulphate and sulphate from deep wells. The d 18O (SO4) from wells exhibits depleted value around -3.60/00 suggesting that 87.5% of sulphate oxygen is derived from groundwater oxygen and 12.5% is derived from atmospheric molecular oxygen in sulphide oxidation reaction. In the other hand, hot springs (except Semurup), crater and fumaroles have enriched value of d 18O (SO4). These enriched values suggest that a higher percentage of atmospherically derived oxygen compared to those from the depth.