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Stefani Wigati
Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta
Chemical Engineering, Chemistry & Bioengineering Chemistry

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THE INFLUENCE OF Si/Al MOLE RATIO OF PRECURSOR SOLUTION ON THE STRUCTURAL PROPERTIES OF MCM-41 FROM FLY ASH Sutarno Sutarno; Yateman Arryanto; Stefani Wigati
Indonesian Journal of Chemistry Vol 3, No 2 (2003)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (146.203 KB) | DOI: 10.22146/ijc.21896

Abstract

The synthesis of MCM-41 from fly ash was done hydrothermally at 100°C for 72 hours using supernatant of fly ash solution, sodium silicate, tetramethylammonium hydroxide (TMAOH) and cetyltrimethyl-ammonium hydroxide (CTMAOH) surfactants. The effect of Si/Al mole ratio of precursor solution on the structural properties of MCM-41 was studied by variation of the volume composition of supernatant and sodium silicate. The surfactant was removed by calcination at 550°C for 5 hours with heating rate 2°C/minute. The as-synthesized products were characterized by X-ray diffraction, infrared spectroscopy, and nitrogen adsorption methods. The XRD pattern proved that the samples were MCM-41 and the higher the Si/Al mole ratio of precursor solution resulted MCM-41 with higher crystallinity. Calcination was able to remove the CTMAOH surfactant. It was identified by the disappearance of the peak at 3000-2850 cm-1, which is characteristic for CTMAOH. The XRD pattern of calcined MCM-41 showed the decreaseof dspacing  and the increase of crystallinity. MCM-41 synthesized with Si/Al mole ratio of precursor solution=44.5 showed the highest crystallinity and has specific surface area=694.5 m2/g, average pore diameter=35Å and pore wall thickness=13.6Å.
Co-Authors Sutarno Sutarno Yateman Arryanto