Yuspian Nur
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Bogor Agricultural University, Darmaga Campus, Kimia Building, Tanjung Street, Bogor 16680

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Optical Sensor for the Determination of Lead(II) Based On Immobilization of Dithizone onto Chitosan-Silica Membrane Yuspian Nur; Eti Rohaeti; Latifah Kosim Darusman
Indonesian Journal of Chemistry Vol 17, No 1 (2017)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (364.923 KB) | DOI: 10.22146/ijc.23560

Abstract

Optical sensor based on incorporation of dithizone and chitosan-silica for the determination of lead (II) ion has been conducted. The optical sensor was made by composite of chitosan and silica in the ratio 2:1. Sol gel technique was chosen to make the membrane because it has some advantages such as its low temperature and chemical reactivity. The sensor has a good selectivity at pH 5 with response times at ± 180 s. Linearity responses was obtained with concentration range from 0.2 to 1.1 ppm with r2 = 0.9921. Average of %RSD on precision and accuracy (%PK) test were 1.46 and 100.96%, respectively. Limit of detection (LOD) and limit of quantification (LOQ) were 0.11 ppm and 0.37 ppm, respectively