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Naser Eltaher Eltayeb
Department of Chemistry, Rabigh College of Science and Arts, P.O. Box 344, King Abdulaziz University, Jeddah, Saudi Arabia
Chemical Engineering, Chemistry & Bioengineering Chemistry

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Manganese(III) Complexes with Tetradentate Schiff Base Ligands: IR, UV/Vis, Electrochemistry and Fluorescence Properties Naser Eltaher Eltayeb
Indonesian Journal of Chemistry Vol 20, No 2 (2020)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (429.215 KB) | DOI: 10.22146/ijc.46395

Abstract

Three trivalent manganese complexes have been synthesized, isolated, and characterized, namely, [MnCl(OH2)(Lx)].nH2O (I-III). Lx is a tetradentate Shiff base ligand, where Lx = LI, 2,2'-{1,2-phenylenebis [nitrilomethylylidene]}bis(phenolate), LII, 2,2'-{1,2-phenylenebis[nitrilomethylylidene]}bis(5-methoxyphenolate), and LIII, 2,2'-{1,2-phenylenebis[nitrilomethylylidene]}bis(4-methoxyphenolate), n = 1, 1.5 and 0 for I, II and III, respectively. These complexes were characterized using IR, elemental analysis and UV-Vis spectroscopy. In addition, the fluorescence, photoluminescence (PL), electrochemistry and thermal stability of these complexes were studied.
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