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Thuy Bich Tran
Institute of Environmental Science, Engineering and Management, Industrial University of Ho Chi Minh City, Vietnam
Chemical Engineering, Chemistry & Bioengineering Chemistry

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Synthesis of Mn-Doped Fe-MOFs with Different Ratios and Its Application for Photocatalytic Degradation of Rhodamine B Dye Kim Ngan Thi Tran; Thuy Bich Tran; Sy Trung Do; Kim Oanh Thi Nguyen; Tan Van Lam
Indonesian Journal of Chemistry Vol 22, No 1 (2022)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.67742

Abstract

Recent trends in environmental remediation have shifted to the use of metal-organic framework (MOF) composites due to their unique structural properties. It is still challenging to diversify MOFs photocatalysts to fulfill application to treat toxic organic pigments. In this study, Fe-MOF bimetallic materials were synthesized by doping Mn2+ ions at different ratios. The structural and morphological characteristics of the materials were analyzed by XRD, UV-Vis, FT-IR, SEM, and UV-Vis DRS methods. Mn/Fe-MOF bimetallic organic framework materials were used to evaluate the photocatalytic degradation of Rhodamine B (RhB) dyes. The results show that, under the same experimental conditions, the RhB degradation efficiency of Mn/Fe-MOF is enhanced than that of the pristine Fe-MOF catalyst under the influence of visible light. After 120 min, the RhB solution was decomposed to 91.78% by combining 0.1 Mn/Fe-MOF, H2O2, and visible light irradiation. At the same time, the presence of H2O2 in the reaction system also showed a strong impact on the efficiency of RhB degradation. The activity from the two metal centers of Mn/Fe-MOF contributes to the formation of a unique structure and composition that can be used as a photocatalyst for colored wastewater treatment.
Co-Authors Kim Ngan Thi Tran Kim Oanh Thi Nguyen Sy Trung Do Tan Van Lam