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Experimental Use of Microwaves in the High Temperature Foaming Process of Glass Waste to Manufacture Heat Insulating Material in Building Construction Lucian Paunescu; Sorin Mircea Axinte; Marius Florin Dragoescu; Felicia Cosmulescu
Journal La Multiapp Vol. 1 No. 3 (2020): Journal La Multiapp
Publisher : Newinera Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37899/journallamultiapp.v1i3.190

Abstract

Abstract The aim of the paper was the experimental manufacture of cellular glass from glass waste and coal ash as raw material and silicon carbide as a foaming agent, using the unconventional microwave heating technique. This heating technique, although known since the last century and recognized worldwide as fast and economical, is not yet industrially applied in high temperature thermal processes. The cellular glass manufacturing process requires high temperatures and the use of microwaves in this process is the originality of the work. The experiments aimed at producing thermal insulating materials with high porosity and low thermal conductivity for building construction similar in terms of quality to those manufactured industrially by conventional techniques, but with lower energy consumption. The obtained samples had adequate characteristics (apparent density 0.22-0.32 g/cm3, porosity 85.5-90.0%, thermal conductivity 0.043-0.060 W/m·K, compressive strength 1.23-1.34 MPa), and the specific energy consumption was low (0.84-0.89 kWh/kg). Theoretically, given the use of microwave equipment on an industrial scale, this consumption comparable in value to that industrially achieved by conventional techniques could decrease by up to 25%.
Manufacture of Cellular Glass Using Oak Leaves as a Foaming Vegetable Agent Lucian Paunescu; Sorin Mircea Axinte; Marius Florin Dragoescu; Felicia Cosmulescu
Journal La Multiapp Vol. 1 No. 4 (2020): Journal La Multiapp
Publisher : Newinera Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37899/journallamultiapp.v1i4.210

Abstract

Abstract The manufacture experimentation of a cellular glass exclusively from mineral waste and natural residues using the unconventional technique of microwave irradiation was the objective of the research whose results are presented in the paper. The originality of the paper results from the use of oak leaves as a vegetable foaming agent as well as the use of microwave energy in heating processes of the raw material powder mixture for manufacturing thermal insulating materials for the building construction. Worldwide, these processes use only conventional heating techniques. The experimental results led to the conclusion that both the use of waste and residues, as well as the unconventional heating technique allow to obtain porous materials with structural homogeneity having apparent densities and thermal conductivities that can decrease up to 0.34 g/cm3, and 0.071 W/m·K respectively. The compressive strength corresponding to the materials with the lowest values of density and thermal conductivity has an acceptable value (1.2 MPa) for the field of application. The specific energy consumption is around 1 kWh/kg, being approximately at the same level with the values of industrial consumptions achieved by conventional techniques.
Manufacturing Ceramic Foams at Very High Temperature by the Unconventional Process of Direct Microwave Heating Lucian Paunescu; Sorin Mircea Axinte; Marius Florin Dragoescu; Felicia Cosmulescu
Journal La Multiapp Vol. 1 No. 4 (2020): Journal La Multiapp
Publisher : Newinera Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37899/journallamultiapp.v1i4.228

Abstract

Abstract SiC ceramic foams were manufactured by direct microwave heating up to 1520 ºC. Silicon carbide (42-68 wt.%), quartz sand as a silica supplier (20-38 wt.%), coal fly ash (12-20 wt.%) and a constant water addition of 15 wt.% were used as starting materials. The ceramic foam samples had semi-open microstructures in which neighboring cells are partially connected to each other and partially closed. Due to the very dense cellular walls and the very low cells size (below 21 μm), the compressive strength had very high values (41.3-56.5MPa), the porosity was within an average value range (52.4-57.6%) and the thermal conductivity and the apparent density had relatively high values. In energy terms, the technique of direct microwave heating was very advantageous, the specific energy consumption being very low (1.04-1.21 kWh/kg) compared to the consumptions achieved by conventional methods. The application field of SiC ceramic foams obtained by the bonding method and using silica as a bonding agent includes hot gas or molten metal filters, porous burners, catalytic supports and others. From the four tested experimental variants, it could be concluded that the optimal sample was that achieved at 1520 ºC with 68% silicon carbide, 20% quartz sand, 12% coal fly ash and 15% water addition, having the porosity of 57.6%, thermal conductivity of 0.174 W/m·K, compressive strength of 56.5 MPa and the equivalent pore size between 9-21 μm.
Glass-ceramic Foams Made of Very High Coal Fly Ash Weight Ratio by the Direct Microwave Heating Technique Lucian Paunescu; Sorin Mircea Axinte; Marius Florin Dragoescu; Felicia Cosmulescu
Journal La Multiapp Vol. 1 No. 4 (2020): Journal La Multiapp
Publisher : Newinera Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37899/journallamultiapp.v1i4.242

Abstract

A high mechanical strength glass-ceramic foam was produced by direct microwave heating at 853 ºC of a very high weight ratio of coal fly ash (82%), calcium carbonate (5%) as a foaming agent, sodium carbonate (13%) as a fluxing agent and water addition (10%). Due to the excellent energy efficiency of the direct microwave heating, the heating rate had a very high value (32 ºC/min), much higher than the heating rate of conventional processes and led to a very low value of the specific energy consumption (0.72 kWh/kg). The physical and mechanical characteristics of the optimal glass-ceramic foam sample were: apparent density of 1.44 g/cm3, porosity of 26.2%, thermal conductivity of 0.281 W/m·K, compressive strength of 41.3 MPa and water absorption of 0.5%. Given the features of the glass-ceramic foam (very high compressive strength, acceptable porosity and thermal conductivity, very low water permeability, fireproof, chemical stability, no-toxicity, etc., the application domain of this material type may include road and railway constructions, bridge abutments and retaining walls, foundations, drainages, sports grounds and other types of constructions that require high mechanical stress.
Glass Foam Made with Silicon Nitride and Manganese Oxide by Microwave Irradiation Marius Florin Dragoescu; Lucian Paunescu; Sorin Mircea Axinte
Journal La Multiapp Vol. 2 No. 2 (2021): Journal La Multiapp
Publisher : Newinera Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37899/journallamultiapp.v2i2.325

Abstract

A high mechanical strength (6.1 MPa) glass foam was produced by sintering/foaming at 830 ºC in an experimental 0.8 kW-microwave oven. The basic raw material was a colorless flat glass waste and the foaming agent was Si3N4 powder (2 wt.%). As an oxygen supplying agent, a MnO2 powder (3.1 wt.%) was used. The main physical, mechanical, thermal and morphological characteristics of the optimal sample were: apparent density of 0.47 g/cm3, porosity of 77.6%, thermal conductivity of 0.105 W/m·K, compressive strength of 6.1 MPa and pore size between 0.15-0.40 mm. The optimal glass foam sample has the required characteristics of a thermal insulation material usable under mechanical stress conditions in civil engineering. The originality of the paper is the application of the unconventional microwave heating technique, faster and more economical, unlike the other papers in the same area published in the literature, followers of the traditional conventional heating technique.
Adequate Correlation between the Physical and Mechanical Properties of Glass Foam Lucian Paunescu; Sorin Mircea Axinte; Marius Florin Dragoescu; Felicia Cosmulescu
Journal La Multiapp Vol. 2 No. 4 (2021): Journal La Multiapp
Publisher : Newinera Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37899/journallamultiapp.v2i4.415

Abstract

The paper presents experimental results obtained in the manufacturing process of a glass foam by adequate correlation between its physical and thermal properties (density, porosity, thermal conductivity) and mechanical (compressive strength) by a slight controlled overheating of the foamed material. Using a powder mixture of glass waste (87-91.5 %), coal fly ash (3-9 %) and silicon carbide (4-5.5 %) microwave heated at 935-975 ºC by this unconventional technique, constituting the originality of the work, was obtained a glass-ceramic foam with moderate compressive strength (1.8-2.6 MPa) and very low thermal conductivity (0.058-0.070 W/m·K). The material overheating generated a homogeneous porous structure characterized by closed cells with relatively large dimensions (without the tendency to join neighboring cells) making it difficult to transfer heat across the material. The foamed product is suitable for the manufacture of thermal insulation blocks for the inner or outer walls of the building without excessive mechanical stress, being an advantageous alternative by comparison with known types of polymeric or fiberglass thermal insulation materials.
Unconventionally Made-Cellular Glass Aggregate Lucian Paunescu; Sorin Mircea Axinte; Felicia Cosmulescu
Journal La Multiapp Vol. 2 No. 6 (2021): Journal La Multiapp
Publisher : Newinera Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37899/journallamultiapp.v2i6.511

Abstract

Improving the original manufacturing process in microwave field of a cellular glass aggregate using a recipe containing colored consumed drinking bottle, calcium carbonate (CaCO3) as an expanding agent, sodium borate (borax) as a fluxing agent and sodium silicate (Na2SiO3) as a binder is shown in the work. The main adopted technological measures were the advanced mechanical processing of residual glass at a grain dimension below 100 μm and especially the use of a high electromagnetic wave susceptible ceramic tube with a wall thickness reduced from 3.5 to 2.5 mm for the protection of the pressed glass-based mixture against the aggressive effect of microwave field and, in the same time, to achieve a preponderantly direct heating with electromagnetic waves. Of the tested variants, a recipe with 1.6 % calcium carbonate, 6 % borax, 8 % sodium silicate and the rest residual glass was determined to be optimal. The cellular glass aggregate had the bulk density of 0.22 g/cm3, heat conductivity of 0.079 W/m·K and compression strength of 5.9 MPa. The specific consumption of energy was very low (0.71 kWh/kg) below the range of reported values of the industrial processes consumption (between 0.74-1.15 kWh/kg).