Piyachat Wattanachai
Department of Chemical Engineering, Faculty of Engineering, Burapha University, Sean Sook, Muang, Chonburi 20131, Thailand

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Open Loop Recycling of Recycled Polypropylene for Motorcycle Saddle Application Piyachat Wattanachai; Benjawan Buasathain; Christian Antonio; Susan Roces
ASEAN Journal of Chemical Engineering Vol 17, No 2 (2017)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1157.426 KB) | DOI: 10.22146/ajche.49556

Abstract

This research investigated the possibility of using polymer blends of virgin andrecycled polypropylene (PP) for a motorcycle saddle application. Three differentrecycled PPs obtained from different sources contained carbon black (CB). Specimenswere prepared by injection molding for mechanical property testing and colorcharacterization whereas scraps from runners were used for thermal property testing. Itwas found that tensile and flexural properties of recycled PPs were better than those ofvirgin PP due to the fact that recycled PPs contained CB which is a reinforcing material.These properties were improved as the amount of recycled PP added increased. Sincerecycled PPs are strong materials, they are hence brittle resulting in lowering impactstrength and percent elongation. The recycled PP sources and compatibility betweenvirgin and recycled PPs strongly influence the blends' properties. The melt flow index ofthe blends increased as the amount of the recycled PP increased because of the shortpolymer chains of recycled PP resulting from earlier processing. Blending virgin PP withrecycled PP not only improves its properties, but also reduces raw material costs in therange of 5-13%. The advantage of open loop recycling is a wider recycled plasticmarket.
Comparison of Thermal Properties of PCB Photoresist Films Cured by Different Techniques Piyachat Wattanachai; Christian Antonio; Susan Roces
ASEAN Journal of Chemical Engineering Vol 15, No 2 (2015)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1104.156 KB) | DOI: 10.22146/ajche.49684

Abstract

The possibility of implementing microwave technology to photoresist film curing which is a major process in the production of electronic printed circuit boards (PCB) was investigated and compared with a conventional curing method, e.g. UV lithography. Since both techniques involved irradiation, hot plate curing which relies on thermal conduction was undertaken to study the effect of a heat transfer approach. Two film thicknesses were studied, i.e. 0.0012 and 0.002 inch, and the effects of curing power and time were investigated. Thermal properties, i.e. percent cure, glass transition temperature (Tg), composition and degradation temperature (Td), were evaluated using a Differential Scanning Calorimeter (DSC) and Thermogravimetric Analysis (TGA) and it was found that the commercial UV irradiation was sufficient to completely cure the thin film but only reached 76% cure for the thicker film, resulting in a lower Tg. The results show that the required processing conditions using a conventional household microwave to obtain almost complete curing were 1,000 Watts and 10 minutes curing time. In addition, improved curing was achieved in the thicker film because microwave can transmit into polar materials whereas UV cannot penetrate very far into the material. The hot plate curing was observed to produce a higher degree of curing and Tg, however, the uniformity of heating was found to be a major limiting factor of this technique. Slight differences in decomposition profiles of the films cured by different techniques implied slight differences in molecular structures. Compared to UV and hot plate curing, microwave technology was demonstrated as a potential curing technique in the production of PCBs due to its ability to efficiently cure thick films resulting in a strong material with high Tg. To apply the technique to other processes, optimal conditions, i.e. power and time, should be further investigated as well as the prevention of hot spots.