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All Journal Jurnal Ilmiah Teknik Mesin Makara Journal of Technology
Yudhistyra Saputra, Yudhistyra
Lampung University
Chemical Engineering, Chemistry & Bioengineering Civil Engineering, Building, Construction & Architecture Electrical & Electronics Engineering Engineering Materials Science & Nanotechnology Mechanical Engineering

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High Temperature Corrosion of Aluminized AISI 4130 Steel with the Different Composition of NaCl/Na2SO4 Deposits Badaruddin, Mohammad; Wang, Chaur Jeng; Saputra, Yudhistyra; Rivai, Abu Khalid
Makara Journal of Technology Vol. 19, No. 2
Publisher : UI Scholars Hub

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Abstract

The high temperature corrosion of AISI 4130 steel can be increased by hot-dip aluminizing coating. The aluminized steel specimens with the deposit composition of 100/0, 30/70, 50/50, 70/30, and 0/100 (wt.%) NaCl/Na2SO4 were oxidized at 750 °C for 1-49 h periods. According to a parabolic rate constant (kp) value, the aluminized steel with deposit composition of 70/30 NaCl/Na2SO4 shows the highest kp value (3.71 × 10-11 g2cm- 4s-1), later followed by the kp value of 3.35 × 10-11 g2cm-4s-1 for 100/0 and the lowest kp value is 7.731 × 10-12 g2cm-4s-1 for 0/100. Whereas, the kp value for the aluminized steel without NaCl/Na2SO4 deposit is around 2.23 × 10-13 g2cm-4s-1. The presence of both salts and their mixtures destroyed protective Al2O3 layer on the aluminized steel, leading to the Fe2O3 growth locally. Whereas, the penetration of sulfur into the Al2O3 scale lead to the formation of Al2S3 and FeS in the aluminide coating. Therefore, the kinetics rate was increased. Furthermore, mixtures of 70 wt. % NaCl in Na2SO4 depositing on the aluminized steel produced the highest parabolic rate constant because the aluminide layer on the steel substrate experienced severe corrosion attack, leading to fail in formation of protective Al2O3 layer.
PENGARUH KOMPOSISI DEPOSIT NaCl/Na 2 SO TERHADAP KOROSI TEMPERATUR TINGGI BAJA AISI 4130 YANG DILAPISI ALUMINIUM 4 Saputra, Yudhistyra; Badaruddin, Mohammad; Zulhanif, .
Jurnal Ilmiah Teknik Mesin FEMA Vol. 2 No. 1 (2014)
Publisher : FT UNILA

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Steel AISI 4130 is a combination steelof 1,0 Cr-0,25 Mo-Fe that mostly used for the component heat axchanger and pipe steam   boiler. However in a high temperature and contain of corrosive gas like klor and sulfur,the endurance of the corrosion of steel AISI 4130 declines. It is important to do a research for increasing the endurance of the corrosion of the steel AISI 4130 with heated Al layered in the surface of steel AISI 4130 Al layered and oxidized in temperature 750°C during periods 1-49 jam. The calibration of the corrosion is done with the variation of deposit NaCl/Na The finding of the research shows that the existence of deposit NaCl/Na2 SO in the steel Al layered brings a large influence oxidation kinetics steel, it is proven through the largest value of parabolic constants of the steel AISI 4130 with Al layered with the comparison of deposit  NaCl/Na4(gr):30/70 is 6,89 × 10-9 g2 cm–4 s–1. Whereas the value of parabolic constants with the comparison of deposit (gr): 100/0 is 2,71 × 10 -9 g2 cm–4 s–1, 50/50 is 6,15 × 10 -9  g2 cm–4 s–12 SO24SO4 , 70/30 is 2,97 × 10 g2 cm –4 s–1 and 0/100 is around 2,60 × 10 -9  g 2 cm –4s–1. The destruction of the protective layer Al in the aluminide layer is caused by the existence of klor dan sulfur from the deposit NaCl/Na2SO4 thattriggersthe growthofiron-rich ovide (FeO).Keywords : steel AISI 4130, Al hot-dip, deposit NaCl, deposit Na2SO4 , Al2O3, iron oxide.
Co-Authors . Zulhanif Abu Khalid Rivai Chaur Jeng Wang, Chaur Jeng