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All Journal Alchemy Jurnal Penelitian Kimia Jurnal Pengabdian Masyarakat Indonesia Molekul: Jurnal Ilmiah Kimia International Journal of Renewable Energy Development
I F Nurcahyo, I F
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Humanities Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Control & Systems Engineering Earth & Planetary Sciences Education Electrical & Electronics Engineering Energy Engineering Environmental Science Materials Science & Nanotechnology Public Health Social Sciences

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PENGARUH KARAKTER KEASAMAN TOTAL DAN PORI KATALIS ZEOLIT ALAM TERIMPREGNASI LOGAM TERHADAP PEMBENTUKAN FRAKSI BENSIN PADA REAKSI HIDRORENGKAH PLASTIK POLIPROPILENA Nurcahyo, I F; Trisunaryanti, Wega; Triyono, Triyono; Wahyuni, Endang Tri
Alchemy Jurnal Penelitian Kimia Vol 7, No 1 (2008)
Publisher : Alchemy Jurnal Penelitian Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Proses hidrorengkah fraksi berat hasil pirolisis plastik polipropilena (td 150-2500C) menjadi fraksi bensin menggunakan berbagai katalis dengan perbedaan keasaman dan karakter pori. Katalis – katalis yang digunakan yaitu zeolit alam (Z), Ni/Z, Pd/Z, NiPd/Z, dan NiPd/Z-Nb2O5. Reaksi dilakukan pada temperatur 4500C dengan perbandingan berat katalis : umpan sama dengan 1:2 menggunakan sistem air. Pada katalis dengan ukuran pori relatif besar, peningkatan keasaman total meningkatkan aktivitas katalis untuk reaktan senyawa hidrokarbon C>12. Pada katalis dengan ukuran pori yang relatif kecil peningkatan keasaman total bukan merupakan faktor penentu aktivitas katalis untuk senyawa hidrokarbon C>12 karena faktor sterik dari ukuran pori.
The Role of The Ni/HZSM-5 Ratio on The Anisole Hydrodeoxygenation Reaction Nugrahaningtyas, Khoirina Dwi; Nurcahyo, I F; Hidayat, Yuniawan; Rahmawati, Fitria; Fadlulloh, Zaki; Heraldy, Eddy; Qurrotul'aini, Nisriina 'Abidah
Molekul Vol 19 No 2 (2024)
Publisher : Universitas Jenderal Soedirman

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20884/1.jm.2024.19.2.11105

Abstract

ABSTRACT. Bio-oil is a renewable energy source with high oxygen levels, and anisole is a chemical widely employed in research to represent it. Catalytic hydrodeoxygenation (HDO) reduces the oxygen content. A catalyst known as nickel-modified HZSM-5 has shown promising results for HDO. Meanwhile, catalyst efficiency depends on the Ni/HZSM-5 ratio. So, this study aims to determine how the Ni/HZSM-5 ratio influences the catalyst's properties, activity, and selectivity in anisole HDO. The Ni/HZSM-5 catalyst was made using the wet impregnation method with various ratios of Ni/HZSM-5. The catalysts were analyzed for their morphology using scanning electron microscopy-energy-dispersive X-ray (SEM-EDX). The diffraction patterns were studied using X-ray diffraction (XRD). Surface area and porosity were determined through gas sorption analysis (GSA). Then, the acidity strength was evaluated via temperature-programmed ammonia desorption (NH3-TPD). The characterization results show Ni was successfully impregnated and distributed evenly in HZSM-5 without changing the primary structure. Adding Ni metal to HZSM-5 increases the surface area of the catalyst but reduces its acid strength. The catalytic performance of the catalysts was then evaluated in a flow reactor at 400 °C, using 15 mL/min H2 gas. The liquid products of the reaction were analyzed using gas chromatography-mass spectroscopy (GC-MS). The results of the catalytic performance show that Ni4.5/HZSM-5 has the highest catalytic activity in anisole conversion. At the same time, Ni6.4/HZSM-5 shows the highest selectivity towards benzene-toluene-xylene (BTX). Keywords: Hydrodeoxygenation, nickel, anisole, heterogeneous catalyst, acidity.
A dry cold sintering to Ta doped-lithium lanthanum zirconate solid electrolyte for all-solid-state lithium metal battery Rahmawati, Fitria; Alaih, Imam Shofid; Rosalin, Azka W; Nurcahyo, I F; Nursukatmo, Hartoto; Nilasary, Hanida; Oktaviano, Haryo S.; Raihan, Edo; Muzayanha, Soraya U.; Handaka, Muhammad F. A.
International Journal of Renewable Energy Development Vol 13, No 5 (2024): September 2024
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/ijred.2024.60351

Abstract

Solid electrolyte is the essential part in all-solid-state battery (ASSB), in which the sintering step is vital to get a dense and high ionic conductivity. However, Li-loss frequently occurs at a high temperature, causing ionic conductivity to drop. This research investigated a dry-cold sintering process (dry-CSP) to Ta doped-LLZO (LLZTO), in which the LLZTO powder was pressed by cold isostatic pressing (CIP) at 40 MPa without solvent addition and then heated at 300oC for 2h. XRD analysis found that LLZTO300C40P remains crystallized in a single cubic with ionic conductivity of (3.02 0.53) x 10-5 Scm-1, which is higher than another result in Al doped-LLZO by CSP uniaxial pressing and with moistened-solvent (wet-CSP). The feasibility was tested by preparing a coin cell with a LiCoO2 cathode and Li metal anode. Cyclic voltammogram of the LCO-LLZTO300C40P-Li ASSB provides a high current density representing a higher electrochemical reaction rate inside the full cell. The battery ran well with an initial charging capacity of 88 mAh/g, and a discharge capacity of 50 mAh/g, providing 56.8 % Coulombic Efficiency. An interface engineering between electrode-solid electrolyte is essential to develop the ASSB performance.
Pelatihan Keselamatan Bahan Gas Berbahaya Untuk Teknisi Mesin Pendingin Nurcahyo, I F; Heraldy, Eddy; Rahmawati, F; Nugrahaningtyas, Khoirina D; Hidayat, Yuniawan
Jurnal Pengabdian Masyarakat Indonesia Vol 4 No 1 (2024): JPMI - Februari 2024
Publisher : CV Infinite Corporation

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.52436/1.jpmi.2031

Abstract

Pelatihan keselamatan bahan gas berbahaya untuk teknisi mesin pending telah dilaksanakan untuk teknisi mesin pendingin yang tergabung dalam paguyuban Aneka Jasa Teknik Surakarta (AJTS). Kecelakaan kerja berkaitan dengan gas freon banyak diberitakan di dunia maya. Paguyuban AJTS merupakan perkumpulan dari teknisi yang banyak berkecimpung sebagai teknisi mesin pendingin terutama AC, kulkas, dan freezer di Solo Raya. Pelatihan ini penting untuk dilakukan untuk membekali teknisi tersebut agar selamat dalam perakitan dan perbaikan mesin pendingin. Pelatihan ini dilaksanakan secara luring meliputi ceramah keselamatan bahan, praktek mengenal MSDS, dan praktek mendeteksi kebocoran gas freon menggunakan alat leaking detektor. Hasil pelatihan antara lain: peserta paham tentang bahaya gas freon dan pencegahan kecelakaan kerja dalam penanganan mesin pendingin. Pelatihan sangat bermanfaat bagi teknisi mesin pendingin terutama peserta pelatihan dan pembaca artikel ini, sehingga keselamatan kerja dapat tercapai.
Co-Authors Alaih, Imam Shofid Eddy Heraldy Endang Tri Wahyuni Fadlulloh, Zaki Fitria Rahmawati Handaka, Muhammad F. A. Khoirina Dwi Nugrahaningtyas Muzayanha, Soraya U. Nilasary, Hanida Nugrahaningtyas, Khoirina D Nursukatmo, Hartoto Oktaviano, Haryo S. Qurrotul'aini, Nisriina 'Abidah Rahmawati, F Raihan, Edo Rosalin, Azka W Triyono Triyono Wega Trisunaryanti Yuniawan Hidayat