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Partial Hydrogenation of FAME on Trickle Bed Reactor using Nickel Catalyst Teguh Budi Santoso; Yuswan Muharam
Fluida Vol 15 No 2 (2022): FLUIDA
Publisher : Department of Chemical Engineering, Politeknik Negeri Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35313/fluida.v15i2.4434

Abstract

FAME (fatty acid methyl ester) is an alternative fuel that is still limited in its application to engines because its low oxidation stability affects the quality of biodiesel storage. A solution to overcome this problem is the partial hydrogenation process in which polyunsaturated FAMEs react with hydrogen, and a catalyst breaks down unsaturated bonds which are oxidation determinants. The use of Ni/Al2O3 catalyst is more advantageous due to its lower cost and higher activity. In this research, partial hydrogenation was carried out in a trickle-bed reactor. The objective of the research is to investigate the effect of operating conditions on FAME conversion. The experimental result shows that the partial hydrogenation of polyunsaturated FAMEs in a trickle bed reactor broke down the polyunsaturated bonds (C19:2) of FAME’s into monounsaturated bonds (C19:1) and saturated bonds (C19:0). The conversion of polyunsaturated FAMEs reaches 8.93% under the inlet pressure of 0.7 MPa, the inlet temperature of 160°C, the hydrogen flowrate of 250 ml/min, the biodiesel flowrate of 0.667 ml/min, and the catalyst size of 1.5 mm.
Tensile Strength and Thermal Properties of Polypropylene/Nano-Bentonite Composites with Maleic Anhydride Coupling Agent Fitria Ika Aryanti; Teguh Budi Santoso
Jurnal Teknologi dan Manajemen Vol. 22 No. 1 (2024): JURNAL TEKNOLOGI DAN MANAJEMEN (FEBRUARY)
Publisher : Politeknik STMI Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.52330/jtm.v22i1.120

Abstract

Polypropylene is the most widely used polymer material in the automotive industry due to its properties such as good rigidity, high melting point, chemical resistance, and easy processability. Polypropylene is usually added with a filler, namely bentonite, to make polypropylene which has better mechanical and thermal properties. The coupling agent is added to improve the adhesion of the matrix with the surface so that the composite component has better durability. To improve the ability of the filler material, bentonite is converted into nanoparticles. Bentonite nanoparticles are expected to have better mechanical, thermal, electrical, and optical properties than particles with micro or macro sizes due to their large surface area. Based on the description above, it is necessary to study the effect of using bentonite nanoparticles with a coupling agent in the form of Maleic Anhydride-g-PP (MAPP) on the tensile strength and thermal properties of polypropylene composites. The variables of this study are the composition variation (weight %) of polypropylene, coupling agent (MAPP), and bentonite nanoparticles of 100:0:0, 95:0:5, 90:5:5, 85:5:10, 92:3:5, and 87:3:10. The method used in this study uses a twin-screw extruder tool with a temperature of 190°C and then tested regarding its tensile strength and thermal properties. The results showed that the addition of nano-bentonite tends to cause an increase in the decomposition temperature of the sample but does not increase the tensile strength of the composite, so it only functions as a polymer composite filler. While based on Differential Scanning Calorimetry (DSC) testing, the enthalpy value decreases with increasing concentration of coupling agent.