Ismunandar Ismunandar
Inorganic and Physical Chemistry Research Division, Faculty of Mathematics and Natural Sciences Institut Teknologi Bandung, Bandung

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Synthesis and Characterization of Bi2TixV1-xO5.5-δ as Electrolyte Material in Solid Oxide Fuel Cell Bambang Prijamboedi; Citra Deliana Dewi Sundari; Rolan Rusli; Ismunandar Ismunandar
Indonesian Journal of Physics Vol 22 No 3 (2011): Vol. 22 No. 3, July 2011
Publisher : Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (704.45 KB) | DOI: 10.5614/itb.ijp.2011.22.3.4

Abstract

Oxide materials of Bi2TixV1-xO5,5-δ have been synthesized by means of conventional solid state reaction method. Substitution of Ti atom for the V sites leads to the formation of single phase Bi2TixV1-xO5,5-δ material with I4/mmm space group of tetragonal structure as well as gives results in large grain size and good sinterability of the ceramic material. With Ti concentration of x = 0.2, sample without the presence of porous could be obtained. The ionic conductivity of Bi2TixV1-xO5,5-δ increases significantly with the presence of Ti atoms. This Ti substitution also reduces phase transition temperatures in Bi2TixV1-xO5,5-δ materials. The conductivity data and scanning electron microscope images show that the Ti concentration in Bi2TixV1-xO5,5-δ could be applied as much as x = 0.2, which is higher than reported before and it still gives better properties.