Harry Budiharjo Sulistyarso
UPN VETERAN YOGYAKARTA

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Investigation and Optimization of Enhanced Oil Recovery Mechanism by Sophorolipid Biosurfactant in Carbonate Reservoir Indah Widiyaningsih; Harry Budiharjo Sulistyarso; Ivan Kurnia; Taufan Marhaendrajana; Tutuka Ariadji
Scientific Contributions Oil and Gas Vol 48 No 3 (2025)
Publisher : Testing Center for Oil and Gas LEMIGAS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/scog.v48i3.1830

Abstract

The Remaining Oil in Place (ROIP) in carbonate rock reservoirs is often substantial. This is due to the tendency of carbonate rocks to be oil-wet in terms of wettability. The oil's inherent property of wetting the rock causes the residual oil to adhere to the rock's pores, making it challenging to extract to the surface. One method to enhanced oil recovery (EOR) is through biosurfactant injection, i.e., sophorolipid, a fungal biosurfactant that possesses the properties of surfactants in general. This study aims to evaluate the effectiveness of sophorolipid biosurfactant injection in enhancing oil recovery in carbonates, as well as to identify the dominant mechanism at work during the injection process and optimize it through coreflooding simulation. This research was conducted through laboratory testing and validation using a simulator, comprising two phases: coreflooding tests and coreflooding simulations. Coreflooding simulation was conducted to reduce the need for coreflooding experiments, which are time-consuming and costly. The simulator used in this research is CMG-GEM with sensitivity parameter and optimization using CMOST. The Sobol Analysis was conducted to assess the sensitivity parameters and identify the primary mechanism of sophorolipid. Then, optimization is achieved by adjusting the parameters, such as sophorolipid concentration, pore volume (PV) injection, and injection rate. Coreflooding sensitivity results show that the dominant parameter is the nonwetting trapping number (DTRAPN), which is closely related to the mechanism of wettability alteration and mix viscosity. The effectiveness of the Sophorolipid mechanism in modifying wettability, enhancing displacement efficiency, and facilitating emulsion formation, hence improving sweeping efficiency. The recovery factor (RF) increased from the coreflooding simulation optimization results, reaching 19%-33%.
Impact of Rhamnolipid Biosurfactants on Chemical Composition, Rheology, and Imbibition Performance of Crude Oils Harry Budiharjo Sulistyarso; Indah Widiyaningsih; Yulius Deddy Hermawan; Joko Pamungkas; Sayoga Heru Prayitno
Scientific Contributions Oil and Gas Vol 48 No 3 (2025)
Publisher : Testing Center for Oil and Gas LEMIGAS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/scog.v48i3.1859

Abstract

The application of biosurfactants in enhanced oil recovery (EOR) has generated significant interest owing to their biodegradability, low toxicity, and effectiveness in modifying oil–rock–brine interactions. Rhamnolipids—glycolipid biosurfactants synthesized by bacterial species—exhibit a distinctive amphiphilic structure that can alter the characteristics of crude oil at both molecular and macroscopic levels. This study offers a novel integrative evaluation of rhamnolipid-induced alterations in chemical composition, rheological properties, and imbibition efficacy of medium and light crude oils. The study utilizes gas chromatography–mass spectrometry (GC–MS) to clarify compositional changes in hydrocarbon fractions, viscosity assessments to measure rheological alterations in oil-biosurfactant mixtures, IFT measurements, and spontaneous imbibition experiments to analyze wettability changes and recovery efficacy. This study simultaneously examines compositional, viscosity, IFT, and capillarity-driven displacement mechanisms across two distinct crude oil categories, contrasting with prior research that focused solely on either compositional or interfacial properties within a single crude oil type, thereby offering comparative insights into biosurfactant–hydrocarbon interactions. The results are anticipated to enhance comprehension of biosurfactant-mediated enhanced oil recovery mechanisms, refine rhamnolipid application methodologies, and connect molecular-level alterations with core-scale oil recovery efficacy. This integrated method provides a novel framework for customizing biosurfactant formulations to particular crude oil varieties, thus improving recovery while preserving environmental sustainability.