Abdul-Razak H. Al-Sudani
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Template Synthesis of Hybrid Schiff Base Complexes of Zn2+, Cd2+, and Hg2+ Ions Abdul-Razak H. Al-Sudani
Journal of Global Pharma Technology Volume 11 Issue 2: 2019
Publisher : Journal of Global Pharma Technology

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Abstract

Five Schiff base complexes of d10 metals were prepared via Template synthesis procedure. This procedure included the synthesis and isolation of intermediate diamine complexes derived from N,N-Diethylethylenediamine; (Et2ne), and appropriate metal salt; MCl2; (M= Zn2+, Cd2+, and Hg2+), followed by the condensation of either of Ortho-phathaldehyde (OPA) or Benzaldehyde with different intermediate diamine complexes of aforementioned metal ions. Moreover, the condensation reaction of the intermediate diamine complexes of the formula [HgCl2 (Et2ne) 2] with OPA failed to produce either the corresponding Schiff base – Mercury- or Organo - Mercury Complex. The identification of the reported Schiff base Metal complexes were  based on Elemental Analyses, Atomic Absorption; FT-IR, Vis-UV; and Molar Conductance. In addition to those techniques, 1H NMR and Mass Spec. were recorded for a couple of the reported complexes.Keywords: Template synthesis, Hybride Schiff Base, Schiff base-d10 metal complexes, Reduction of mercury diamine complex, N,N-Diethylethylenediamine,  Benzaldehyde, o- Phathaldehyde.