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Reinforcement of Quaternary Ammonium Modified Silica (QAMS) with Magnetite and its Application by Solid Phase Adsorption (SPA) to Adsorb Chromate Ions Ngatijo Ngatijo; Restina Bemis; Abdul Aziz; Rahmat Basuki
Jurnal Kimia Sains dan Aplikasi Vol 23, No 10 (2020): Volume 23 Issue 10 Year 2020
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (4000.292 KB) | DOI: 10.14710/jksa.23.10.338-345

Abstract

Chromium (VI) in the form of chromate anions that have toxic properties needs to be overcome. This study aims to reinforce cationic sorbent quaternary amine-modified silica with magnetite (QAMS-Fe3O4) to adsorb chromate ions. QAMS prepared by reflux methylation ammine modified silica (AMS) obtained from destruction silicate from rice husk ash followed by the addition of 3-APTMS. Characterization QAMS-Fe3O4 by FT-IR showed successfully of methylation process indicated by disappearing absorbance at 1388 cm-1, and emerging absorbance at 2939 cm-1 in QAMS and QAMS-Fe3O4 indicated a transformation of N-H from -NH2 group to [-N+(CH3)3]. XRD analysis denotes 2θ = 30.15°, 35.53°, 43.12°, 57.22°, and 62.90° (JCPDS No. 00-033-0664) fathomed as a characteristic peak of magnetite. SEM-EDX reveals the homogenous topological spherical form with an average particle size 0.006 µm that is dominated by Si element (52.81%) with magnetic moment value = 34.1 emu/g. The stability test shows that this material stable in an acid condition. The adsorption of chromate ions was conducted by the SPA method. Optimal pH obtained by pH range 4-7 with more than 90% adsorbed chromate ions. Variation of increasing series flow rate from 0.05 to 1.5 mL min-1 resulted in decreased adsorbed chromate ions. The use of SPA methods offered simpler and easier handling than the batch method without overriding the adsorption process effectiveness.
A Survey On Causal Consistency Implementation In Geo-Replicated Cases Muhamad Syukron; Chilyatun Nisa; Abdul Aziz; Royyana Muslim Ijtihadie
IJCONSIST JOURNALS Vol 5 No 2 (2024): March
Publisher : International Journal of Computer, Network Security and Information System

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33005/ijconsist.v5i2.145

Abstract

Distributed storage systems are a fundamental component of large-scale internet services. To meet the in-creasing needs of users regarding availability and latency, the design of data storage systems has developed into data replication techniques, one of which is geo-replication. Causal consistency is an attractive method for storing geo-replicated data because it is at the crucial point between ease of programming and resulting performance. This method also enables high availability and low latency. However, when implemented into cloud storage, there are limitations regarding throughput and costs. We surveyed several models using methods related to causal consistency in geo-replication cases designed by previous researchers. The mod-els used were derived from papers on causal consistency in geo-replication cases published within the last five years. In this study, we compared the performance of previously designed models based on their performance results. The results of this study are grouping models based on throughput and latency performance obtained.
Nickel-vanadium impregnated to hydrotalcite for hydrocracking of waste cooking oil Lenny Marlinda; Sugeng Priyanto; Peri Oktiarmi; Maja Pranata Marbun; Aisha Andini Indira Dewi; Sudibyo Sudibyo; Indri Yati; Abdul Aziz; Reva Edra Nugraha; Muhammad Al Muttaqii
International Journal of Renewable Energy Development Vol 15, No 3 (2026): May 2026
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/ijred.2026.61972

Abstract

Hydrotalcite (HT) is a type of clay mineral belonging to the group of layered double hydroxides (LDHs) or anionic clays, which has a layered structure like brucite (Mg(OH)₂), but some of the divalent cations (such as Mg²⁺) are replaced by trivalent cations (such as Al³⁺). HT as a heterogeneous catalyst is particularly attractive because it is easy to separate and resistant to high temperatures. HT as a catalyst can be used in hydrocracking reaction to produce biofuel. Metal impregnation on HT is very promising to enhance catalytic activity especially with the bifunctional mechanism of catalyst. Ni-V metal impregnation has been successfully carried out on HTc using wet impregnation method which is indicated by the results of X-Ray Diffraction (XRD) which shows the emergence of typical peaks of both metals and HTc in 2θ = 35‒70⁰ for HTc, 2θ = 37.22⁰ (NiO) and 37.35⁰ (V2O5) regions, 2θ = 43.58⁰ for NiO, 2θ = 61.26⁰ (V) and 63.07⁰ (Ini). Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX) show a shape that is consistent with the characteristics of HT, namely the shape of the particles layered overlapping each other. In addition, the particle size of HTc is quite small with a scale of 1 μm indicating a particle size of hundreds of nanometers. EDX mapping shows that Ni and V have been dispersed evenly on the HTc surface. Based on the results of N2 adsorption-desorption isotherms, it shows that mesopores are formed which are characterized by hysteresis loops. Ni-V metal impregnation increases the surface area up to 19.915 m2/g and the pore diameter up to 37,642 nm. The results of the Waste Cooking Oil (WCO) hydrocraking reaction show that Ni-V metal impregnation can reduce the carboxylic acid composition up to 67.81% and increase hydrocarbons up to 15% at 10% Ni-V/HTc 1:2.