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Meilana Dharma Putra
Chemical Engineering Department, Universitas Lambung Mangkurat Banjarmasin
Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering

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Inovasi Penyisipan Karbon dari Pektin pada Pembuatan Membran Interlayer-free Silika-pektin Amalia Enggar Pratiwi; Muthia Elma; Meilana Dharma Putra; Agus Mirwan; Aulia Rahma; Erdina Lulu Atika Rampun
Jurnal Kimia Sains dan Aplikasi Vol 22, No 3 (2019): Volume 22 Issue 3 Year 2019
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2567.594 KB) | DOI: 10.14710/jksa.22.3.93-98

Abstract

Water scarcity is the main issues in Indonesia especially for coastal areas. As a consequence, the water has high salinity of >50.000 ppm salt concentration where an appropriate treatment is necessary before consumed. In this case, desalination process could be carried out using inorganic silica membranes. However, during the process the pore of silica membranes were collapsed due to the directly contact of pores to water molecules for a long term performance. Thereby, in this work the innovation of membrane fabrication using carbon templated in silica matrices has been successfully fabricated. Literally, the carbon templates could be improving the membrane hydro-stability. The interlayer-free silica-pectin membrane was fabricated using TEOS as silica precursor and carbon templated from pectin apple. All membranes waere calcined in variance temperature of 300 and 400°C via Rapid Thermal Processing (RTP). The FTIR results show some functionalization of siloxane, silanol and a new bond of silica-carbon. Whereas, the SEM images show the membrane morphology that the membrane not dense and crack-free with thin film's thickness of ~ 1 μm. An excellent condition of interlayer-free silica-pectin membrane was obtained at pectin concentration of 2.5 %wt. (300°C) and 0.5 %wt. (400°C) with highest functionalization of siloxane and silica-carbon bonds. The existence of silica-carbon bonds were capable to enhancing the membrane hydro-stability. In addition, the carbon chains were contributed to form a smaller pores but also robust pore structures. Those fabricated membranes were shown a good promising due to fast and low cost fabrication with high quality to applicate in seawater desalination.
Interlayer-free Membran Silika Pektin untuk Pervaporasi Air Rawa Asin Erdina Lulu Atika Rampun; Muthia Elma; Isna Syauqiah; Meilana Dharma Putra; Aulia Rahma; Amalia Enggar Pratiwi
Jurnal Kimia Sains dan Aplikasi Vol 22, No 3 (2019): Volume 22 Issue 3 Year 2019
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2440.738 KB) | DOI: 10.14710/jksa.22.3.99-104

Abstract

Wetland in South Kalimantan is one of surface water sources to provide clean water. However, seawater intrusion has spread into the wetland aquifer and reduce the quality of water. Silica-pectin membrane is a promising technology for desalination. The membranes were tested for desalination by pervaporation at room temperature (~25 °C). During pervaporation process, the water contacts to membrane and the separation is started to occurs as vapour phase by maintaining vacuum pressure (~1 bar). The permeate was collected in the cold trap after condensed using nitrogen liquid. The purpose of this research was to investigate the performance of interlayer-free silica pectin membrane for wetland saline water. Experimental results shows the fluxes of membrane are 0.35 and 0.19 kg.m-2 h-1 ( pectin 0%wt); 0.23 and 0.16 kg.m-2 h-1 (pectin 0.1%wt); 0.58 and 3.63 kg.m-2 h-1 (pectin 0.5%wt); 3.40 and 0.12 kg.m-2 h-1 (pectin 2.5%wt) calcined at 300 and 400 °C, respectively. Natural organic matter (NOM) and salt concentration in wetland saline water can reduce the fluxes up to (~98%). Nevertheless, overall salt rejection of membranes achieved >99%. It was found that low calcination gives better performance at high pectin concentration. While pectin concentration was limited at high calcination.
Co-Authors Agus Mirwan Amalia Enggar Pratiwi Aulia Rahma Erdina Lulu Atika Rampun Isna Syauqiah Muthia Elma