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All Journal Bulletin of Chemical Reaction Engineering & Catalysis
S. Mukhopadhyay
Chemical Engineering Division & Solid State Physics Division, Bhabha Atomic Research Centre (BARC), Mumbai 400085, Maharashtra
Chemical Engineering, Chemistry & Bioengineering Chemistry

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Selective hydrogenation of Dibenzo-18-crown-6 ether over highly active monodisperse Ru/γ-Al2O3 nanocatalyst Y. R. Suryawanshi; M. Chakrabortya; S. Jauhari; S. Mukhopadhyay; K. T. Shenoy; D. Sen
Bulletin of Chemical Reaction Engineering & Catalysis 2015: BCREC Volume 10 Issue 1 Year 2015 (April 2015)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.10.1.7141.23-29

Abstract

Ru/γ-Al2O3 nanocatalyst with different metal loading was synthesized by microwave irradiated sol-vothermal technique. Synthesized nanocatalyst (4-14 nm of metal particle size)was then successfully implemented for the hydrogenation of Dibenzocrown-18-crown-6 ether (DB18C6) at 9 MPa, 393 K tem-perature and 3.5 h. It was observed that the metallic small nanoclusters produced at 4 wt% metal con-centration exhibited higher catalytic activity and resulted 96.7% conversion with 100% selectivity to-wards cis-syn-cis-dicyclohexano-18-crown-6 ether (CSC DCH18C6). © 2015 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)
Co-Authors D. Sen K. T. Shenoy M. Chakrabortya S. Jauhari Y. R. Suryawanshi