Zaqiya Artha Zahara
Magister Programme in Environment Management, Sriwijaya University, Palembang, South Sumatra, 30139, Indonesia

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Layered Double Hydroxide Zn/M3+ (M3+= Al and Cr) as Highly Efficient Adsorbent of Heavy Metal Pb(II) Zaqiya Artha Zahara; Luna Silaen; Normah Normah; Novie Juleanti; Neza Rahayu Palapa
Indonesian Journal of Material Research Vol. 1 No. 1 (2023): March
Publisher : Magister Program of Material Science Graduate School of Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/ijmr.2023114

Abstract

Synthesis of Zn-Al and Zn-Cr LDHs in this research was successfully carried out. The sucsessfully results can be seen from the XRD characterization which displays diffraction angles at 10 and 60 which indicates the presence of layered structures and anions. FT-IR data displays the presence of nitrate groups at wavenumber 1381 cm−1. BET data shows surface area of Zn-Al and Zn-Cr at 1.965, 31.638 m2/g, corresponding. pHpzc determination of Zn-Al material gets a pH below pHpzc which is 6.2 while Zn-Cr is at pHpzc which is 7.6. Able of Zn (Al/Cr) as adsorbent to adsorp Pb(II) was investigated through several parameters such as kinetics, isotherms, thermodynamics. Kinetic Adsorption for Zn-Al inclined follow PSO, while Zn-Cr follow PFO. Isotherm parameter for Zn-Al and Zn-Cr is Freundlich with a maximum adsorption capacity 74.127 mg/L, and 27.027 mg/L. Thermodynamic process shows that Zn-Al and Zn-Cr LDHs take place in endothermic and spontaneously.
Ni-Cr Layered Double Hydroxide/Microcrystalline Cellulose Composite as Adsorbents for Malachite Green Dye Rotua Natalia Manalu; Zaqiya Artha Zahara; Risfidian Mohadi
Indonesian Journal of Material Research Vol. 1 No. 2 (2023): July
Publisher : Magister Program of Material Science Graduate School of Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/ijmr.2023128

Abstract

Malachite green dye in industrial wastewater can be removed by the adsorption method. The adsorbents used in the adsorption method were Ni-Cr LDH, microcrystalline cellulose, and Ni Cr LDH/microcrystalline cellulose composite. Regeneration process of malachite green dye with the Ni-Cr/microcrystalline cellulose adsorbent resulted in the adsorbent having the highest percent adsorbed when compared to Ni-Cr LDH and microcrystalline cellulose adsorbents. This is proof that Ni-Cr/microcrystalline cellulose LDH composite adsorbent can be used repeatedly as much as five cycles. Ni-Cr LDH material and Ni-Cr/microcrystalline cellulose LDH composite were synthesized by the coprecipitation method and were successfully carried out by XRD characterization to see the stability of the structure. The results of XRD characterization of Ni-Cr/microcrystalline cellulose composite showed peaks at diffraction angles of 11°(003), and 60°(110) which are typical regions of LDH and at diffraction angle of 22°(020) which is a typical area of microcrystalline cellulose material. Ni-Cr LDH, microcrystalline cellulose and Ni-Cr/microcrystalline cellulose get optimum pH at 7 with wavelength malachite green at 618.8 nm, kinetic equation following PSO and isotherm following Freundlich with capacity maximum until 129.870 mg.g−1. FT-IR spectra display groups found in LDH and composites including O-H, NO3−, M-O also microcrystalline cellulose have groups C-O and C-H. SEM characterization found out the biggest particle size is 1,954 µm as much as 72 and EDX composite material contains elements of O, C, Ni, Cr, Na, and N.