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All Journal Jurnal Kartika Kimia Makara Journal of Science
Novianti, Nurul Fitri
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Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Education

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Isolation of Lignin from Sugarcane Bagasse as an Adsorbent for Chromium Ion Berghuis, Nila Tanyela; Novianti, Nurul Fitri; Ratri, Paramita Jaya
Makara Journal of Science Vol. 27, No. 3
Publisher : UI Scholars Hub

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Abstract

The waste generated in metal coating and leather tanning industries contribute to water pollution owing to the use of Cr metal in production processes. The utilization of lignin from natural base materials in the form of bagasse can reduce unwanted waste from production processes and adsorb Cr ion waste. In this study, lignin was successfully isolated from bagasse waste and then carbonized and applied in Cr metal absorption. Lignin and lignin carbon as an absorbent were characterized using Fourier-transform infrared spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). The ability of bagasse lignin and carbon lignin to absorb Cr ion waste was evaluated by monitoring mass fluctuation, contact time, and pH. The optimal conditions for adsorption were determined as follows: 0.015 g, 90 min, and pH 6. The adsorption isotherm followed the Freundlich model, and the adsorption kinetics followed the pseudo-first-order model. Furthermore, adsorption thermodynamics showed that the reaction proceeded spontaneously, and the disorder degree increased in the adsorption system
Adsorption Ability of Bagasse Lignin (LB), Bagasse Lignin Carbon (LBF), and Amination Lignin (LA) for Chrome (III) Berghuis, Nila Tanyela; Novianti, Nurul Fitri; Ratri, Paramita Jaya
Jurnal Kartika Kimia Vol 6 No 1 (2023): Jurnal Kartika Kimia
Publisher : Department of Chemistry, Faculty of Sciences and Informatics, University of Jenderal Achmad Yani

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26874/jkk.v6i1.201

Abstract

Analyzing the Cr(III) adsorption properties of bagasse lignin (LB), bagasse lignin carbon (LBF), and lignin amine (LA). Variable adsorption studies were performed, including variations in mass, contact time, and pH. The adsorption ability test was carried out first by varying the mass of the adsorbent to determine the optimum mass of each adsorbent LB, LBF, and LA for the Cr(III) adsorbate. The ability of lignin adsorbents (LB, LBF, and LA) to adsorb Cr(III) was optimum at 0.015 g adsorbent mass contact time of 90 minutes, and the adsorbate solution had a pH of 6. The adsorption capacity (Qm) value for bagasse lignin adsorbent (LB) was 8.6050 mg/g at 30°C, bagasse carbon lignin (LBF) was 9.8717 mg/g (30°C), and ammine lignin (LA) with the highest value is 9.9800 mg/g (35 °C).
Co-Authors Berghuis, Nila Tanyela Ratri, Paramita Jaya