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Fainan Failamani
Inorganic and Physical Chemistry Research Division, Faculty of Mathematics and Natural Sciences, Bandung Institute of Technology, Jalan Ganesha 10, Bandung, 40132, Indonesia
Astronomy Chemistry Earth & Planetary Sciences Mathematics Physics

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Structural and Photoluminescence Properties of Ca2+-Substituted Self-Activated Photoluminescence Material of Na2TiSiO5 Dzaky Dian Ruhimat; Fainan Failamani; Bambang Prijamboedi
Journal of Mathematical and Fundamental Sciences Vol. 55 No. 2 (2023)
Publisher : Directorate for Research and Community Services (LPPM) ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.math.fund.sci.2023.55.2.6

Abstract

The effects of Ca2+ substitution on the structural and optical properties of Na2TiSiO5 were studied. It was expected that the Ca2+ ions would replace Na+ ions and change the coordination of Ti4+-O2- as a luminescence center. Na2(1‑x)CaxTiSiO5 (x = 0.00, 0.50, 1.00) samples were synthesized using the solid-state method, and their structural properties, the local Ti4+-O2- coordination, the absorption spectra, and the photoluminescence properties were studied. The electronic structure of Na2(1-x)CaxTiSiO5 with x = 0.00 and 1.00 was also calculated using the Full Potential Linear Augmented Plane Wave (FP-LAPW) method to explain some of the observed properties. The Ca2+ substitution resulted in a phase transformation from an orthorhombic to a monoclinic structure. The number of TiO6 octahedra increased with the increase of Ca2+ and correlated with the decrease of PL emission intensity of the Na2(1‑x)CaxTiSiO5 samples. The Ti-3d bands in the CaTiSiO5 were more dispersive than in the Na2TiSiO5 and were responsible for the PL emission intensity reduction.
Co-Authors Bambang Prijamboedi Dzaky Dian Ruhimat