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Enhancing the Energy Content of Melawan Coal through H2SO4 and NaOH Demineralization Ngulde, Aliyu Buba; Wan Ab Karim Ghani, Wan Azlina; Nawi, Nazmi Mat; Rashid, Umer; Silas, Kiman
Indonesian Journal of Chemistry Vol 25, No 3 (2025)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.100059

Abstract

The objective of this study was to compare the calorific values, proximate analysis, ultimate analysis, SEM-EDX, XRF, FTIR spectroscopy, and TGA of the control feedstock and coal samples treated with different acid-alkali formulations. We also evaluated the effectiveness of the acid and alkali treatments, individually and in combination, on the structural and chemical properties of Melawan coal. The TGA results indicated that all treated coal samples showed reduced weight loss compared to raw coal, indicating the removal of minerals and volatile components owing to the treatment processes. Based on the DTG curve, the combination treatment (acid followed by base) somewhat stabilizes the coal, leading to a broader and less intense peak. EDS analysis revealed that both H2SO4 and NaOH treatments, individually and in combination, significantly altered the elemental composition of the coal. According to FTIR analysis, the presence of carbonyl groups can affect the performance of coal in processes such as gasification, pyrolysis, or combustion, making it a key functional group of interest for evaluating post-treatment coal properties. The removal of mineral impurities can lead to a higher calorific value, making coal more suitable for energy generation applications.
Baobab Leaf Powder Efficacy as Turbid Water Treatment Biocoagulant Gram, Vahyela; Kasinath, Archana; Abubakar, Abdulhalim Musa; Pandit, Gaurav Kumar; Ngulde, Aliyu Buba; Saka, Tahiru; Mustapha, Zanna
Indonesian Journal of Innovation and Applied Sciences (IJIAS) Vol. 4 No. 1 (2024): February-May
Publisher : CV. Literasi Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.47540/ijias.v4i1.1367

Abstract

The high cost of treated water makes most rural communities resort to readily available sources that are normally of low quality, which exposes them to waterborne diseases in the process. In the present study, various doses of baobab (Adansonia digitata) leaf powder coagulant (i.e., 0.1, 0.2, and 0.3g per 50 mL turbid water) were added to the surface water sample collected. It was found that increasing the coagulant doses results in either a decrease or increase in the measured parameters, such as pH, turbidity, and electrical conductivity (EC). At constant 30 min coagulation time, pH and EC of the turbid water samples taken were within WHO standards. However, the labeled sample fed with 0.3g of baobab leaf powder coagulant gave the lowest turbidity of 78.7 NTU. A reduction in final turbidity is a clear indication of the coagulation capabilities of baobab leave powder. With this study, baobab leave (as a potential coagulant) is a new addition to the literature, apart from its seed and pulp which have been experimented with previously. Natural coagulants contain some chemicals whose effect on the resulting treated water needs to be examined. If need be, an additional treatment unit must be set up to adsorb or remove those contaminants from the water before proper use.