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Modeling, Simulation and Extraction of Model Parameters of Dye-Sensitized Solar Cells (DSSCs) using Different Single-Diode Models Yerima, Jamu Benson; William, Dunama; Babangida, Alkali; Ezike, Sabastine Chinedu
Computational And Experimental Research In Materials And Renewable Energy Vol 6 No 1 (2023): May
Publisher : Physics Department, Faculty of Mathematics and Natural Sciences, University of Jember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.19184/cerimre.v6i1.33762

Abstract

Modeling, simulation and extraction of model parameters of four DSSCs was carried out using four different models. The results show that model parameters depend on of the types of models and dyes (or DSSCs). Also, the fewer the number of model parameters the lesser the computation efforts and knowledge about the internal features of the photovoltaic system and vice versa. In addition, the photocurrent Iph of a DSSC is constant for all models. Furthermore, the diode reverse saturation current Io is inversely proportional to the absolute values of the series resistance Rs and shunt resistance Rsh. Moreover, the modified diode ideality factor depends on the number of model parameters and nature of dye/DSSC. However, models with higher number of model parameters (4 and 5) involving resistances manifest parameter irregularity. Nevertheless, the negative sign or complexity of the model parameters does not render them undesirable elements for researchers to use them in their application. Thus, the overall result shows that all the models used produced good I-V curve fit for all the solar cells studied irrespective of the presence of parameter irregularity.Keywords: Modeling, Simulation, Model parameter, DSSCs, Single diode model, Parameter irregularity.
Analytical Methods for Mathematical Modeling of Dye-Sensitized Solar Cells (DSSCs) Performance for Different Local Natural Dye Photosensitizers Yerima, Jamu Benson; Ezike, Sabastine Chinedu; William, Dunama; Babangida, Alkali
Computational And Experimental Research In Materials And Renewable Energy Vol 5 No 2 (2022): November
Publisher : Physics Department, Faculty of Mathematics and Natural Sciences, University of Jember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.19184/cerimre.v5i2.33499

Abstract

In this paper, a new approach to generate the modified ideal diode factor of solar cells was developed which overcomes the problem of assuming its value a constant. Five models were employed to calculate the five-model parameters of one standard solar cell and fourteen DSSCs with varying photosensitizers. The results exhibit the conversion efficiencies of the solar cells studied lies in the range 2.57% ≤ η ≤ 0.03%. In particular, the standard cell has the highest efficiency 3.02% followed by DSSCs with photosensitizers: bitter gourd (2.57%), mango (1%), and bougainvillea (0.83%). Also, the five model parameters calculated are all positive for El Tayyan model and the rest of the models show discrepancies of varying degrees. Furthermore, despite the existence of these discrepancies, the results reveal good fit between the model data and experimental data I-V curves. This suggests the tendency or possibility that irregular parameters may be desirable for some applications. Thus, the discrepancies found in the estimated parameters can serve as a vital assessment criterion and tool for researchers and engineers in selecting the appropriate parameter estimation method for their applications. Keywords: Analytical methods, Mathematical modeling, DSSCs, Photosensitizers, Irregular parameters, Conversion efficiency.