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All Journal Jurnal Presipitasi : Media Komunikasi dan Pengembangan Teknik Lingkungan Journal of Mathematical and Fundamental Sciences
Purwanto, Agus
Department Of Chemical Engineering, Faculty Of Engineering, Sebelas Maret Universitas, Jl. Ir. Sutami 36A, Surakarta, Central Java 57126
Agriculture, Biological Sciences & Forestry Astronomy Chemistry Earth & Planetary Sciences Mathematics Physics

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Metal-Organic Frameworks Based on Zinc(II) and Benzene-1,3,5-Tricarboxylate Modified Graphite: Fabrication and Application as an Anode Material in Lithium-Ion Batteries Witri Wahyu Lestari; Wulan Cahya Inayah; Fitria Rahmawati; Larasati Larasati; Agus Purwanto
Journal of Mathematical and Fundamental Sciences Vol. 52 No. 1 (2020)
Publisher : Institute for Research and Community Services (LPPM) ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.math.fund.sci.2020.52.1.6

Abstract

This research was aimed at synthesizing metal-organic frameworks (MOFs) based on zinc(II) and a benzene-1,3,5-tricarboxylate (BTC) linker in combination with graphite as anode material in lithium-ion batteries. The MOFs were prepared using sonochemical and solvothermal methods, which led to different materials: [Zn3(BTC)2·12H2O] (MOF 1) and [Zn(BTC)·H2O·3DMF] (MOF 2). The produced materials were characterized by powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermogravimetric/differential thermal analysis (TG/DTA), and a battery analyzer. Refinement of the XRD data was performed using the Rietica and Le Bail method. Sharp and intense peaks indicated that the materials had a high degree of crystallinity. The morphology of the materials as analyzed by SEM was cubic, with an average crystal size of 8.377 ± 4.276 µm for MOF 1 and a larger size of 16.351 ± 3.683 µm for MOF 2. MOF 1 was thermally stable up to 378.7 °C while MOF 2 remained stable up to 341.8 °C, as demonstrated by thermogravimetric analysis. The employment of the synthesized materials as anode in a lithium ion battery was proved to yield higher specific capacity and cycle stability compared to those using a graphite anode. The lithium-ion battery with 5 wt% MOF 1 exhibited the highest performance with an efficiency of 97.28%, and charge and discharge specific capacities of 123.792 and 120.421 mAh/g, respectively.
Utilization of Spent Nickel Catalyst as Raw Material for Ni-Rich Cathode Material Shofirul Sholikhatun Nisa; Anisa Raditya Nurohmah; Cornelius Satria Yudha; Hanida Nilasary; Hartoto Nursukatmo; Endah Retno Dyartanti; Agus Purwanto
Jurnal Presipitasi : Media Komunikasi dan Pengembangan Teknik Lingkungan Vol 18, No 2 (2021): July 2021
Publisher : Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (526.609 KB) | DOI: 10.14710/presipitasi.v18i2.349-357

Abstract

Spent nickel catalyst will be harmful to the environment if it is not processed or used properly. In fact, this waste still has a high nickel content. The treatment of spent nickel catalysts has been widely reported, but limited to nickel extraction. Since the lithium-ion batteries demand is continued to increase, then nickel is the most sought-after metal. Consequently, nickel from spent nickel catalysts could be developed as secondary source for lithium-ion battery cathode. This study aims to utilize spent nickel catalysts into more valuable materials. Nickel that has been extracted and mixed with Mn and Co has been used as raw material for nickel-rich cathode, namely NMC. Nickel extraction and NMC synthesis were using the acid leaching method followed by co-precipitation[WI1] [SSN2] . Based on the functional test performed in this work, nickel from spent nickel catalyst can be applied to Li-ion batteries. The sintering temperature that gives good characteristics and electrochemistry was found 820oC. The galvanostatic charge-discharge test gave specific capacity results for NMC of 110.4 mAh/g. The cycle test showed that NMC synthesized from spent nickel catalyst can be carried out up to 50 cycles with a capacity retention of 87.18%.
Co-Authors Adrian Nur Adrian Nur Anatta Wahyu Budiman Anisa Raditya Nurohmah Arif Jumari Atika Aulia Novita Sari Cornelius Satria Yudha Cornelius Satria Yudha Diajeng Putri Suciutami Endah Retno Dyartanti Endah Retno Dyartanti Fitria Rahmawati Hanida Nilasary Hartoto Nursukatmo Hendri Widiyandari Inayati Inayati Larasati Larasati Luthfi Mufidatul Hasanah Luthfi Mufidatul Hasanah Luthfi Mufidatul Hasanah Shofirul Sholikhatun Nisa Soraya Ulfa Muzayanha Soraya Ulfa Muzayanha Soraya Ulfa Muzayanha Tika Paramitha Witri Wahyu Lestari Wulan Cahya Inayah