Manuaba, I. B. P.
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PEMBUATAN ARANG BAMBU TABAH (Gigantochloa nigrociliata) DENGAN AKTIVATOR ZnCl2 SEBAGAI ADSORBEN CONGO RED Manurung, M.; Hartanto, S. B.; Manuaba, I. B. P.
Jurnal Kimia (Journal of Chemistry) Vol. 18, No.1, Januari 2024
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24843/JCHEM.2024.v18.i01.p06

Abstract

Arang aktif merupakan material unik sebab mampu menjerap ion positif, negatif, dan netral dengan baik. Penelitian bertujuan untuk mempelajari adsorpsi congo red menggunakan arang bambu tabah, tanpa aktivasi dan dengan aktivasi. Penelitian dimulai dengan membuat arang bambu tabah secara pirolisis. Sebagian arang diaktivasi dengan ZnCl2 secara impregnasi, sehingga didapatkan arang aktif. Arang tanpa aktivasi dan teraktivasi dikarakterisasi gugus fungsinya. Kapasitas adsorpsi masing-masing adsorben juga diukur setelah mengoptimasi beberapa parameter adsorpsi seperti waktu kontak, jumlah massa adsorben, pH larutan, dan suhu. AB2 yaitu arang teraktivasi, memiliki kemampuan terbaik dalam mengadorpsi congo red dengan nilai kapasitas adsoprsi sebesar 64,472 mg/g, waktu kontak 120 menit, massa adsorben 0,1 g, suhu 30 oC dan pH 2. Kapasitas adsorpsi AB0, AB1, dan AB2 secara berturut-turut adalah 31,137; 61,855; dan 64,472 mg/g. Arang bambu tabah memiliki potensi yang baik untuk menjerap congo red dari larutan. Kata kunci: Adsorpsi, Arang Aktif, Bambu Tabah, Congo Red ABSTRACT Activated charcoal is a unique material because it can absorb positive, negative, and neutral ions well. This research aimed to study the adsorption of Congo red by using inactivated and activated Tabah bamboo charcoals. The research began by preparing Tabah bamboo charcoal using pyrolysis. Some charcoal was activated with ZnCl2, by impregnation to obtain activated charcoal. The functional groups of inactivated and activated charcoal were characterized. The adsorption capacity of each adsorbent was also measured after optimizing several adsorption parameters such as contact time, adsorbent mass amount, solution pH, and temperature. AB2, namely activated charcoal, had the best ability to adsorb Congo red with an adsorption capacity value of 64.472 mg/g, contact time of 120 minutes, adsorbent mass of 0.1g, temperature of 30 ?, and pH 2. The adsorption capacities of AB0, AB1, and AB2 are respectively 31,137; 61,855; and 64.472 mg/g. Tabah bamboo charcoal has good potential to absorb congo red from the solution. Keywords: Activated Charcoal, Adsorption, Congo Red, Tabah Bamboo
KANDUNGAN HARA MAKRO SETELAH PENAMBAHAN PUPUK KOMPOS BLOTONG PADA TANAH PERKEBUNAN Rahmah, I.; Suarya, P.; Manuaba, I. B. P.; Ariati, N. K.
Jurnal Kimia (Journal of Chemistry) Vol. 18, No.1, Januari 2024
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24843/JCHEM.2024.v18.i01.p12

Abstract

Blotong atau filter cake merupakan kotoran nira tebu dari proses pembuatan gula. Namun, blotong dapat dimanfaatkan menjadi pupuk organik karena kandungan hara dalam blotong cukup tinggi. Misalnya kandungan C, N, P, dan K yang dapat menjadi sumber hara serta meningkatkan kualitas tanah. Penelitian ini bertujuan untuk mengetahui peningkatan unsur hara C, N, P, dan K pada tanah setelah pemberian pupuk blotong. Metode yang digunakan dalam penelitian ini yaitu metode Walkley and Black untuk penetapan hara C, metode Kjeldahl untuk penentuan hara N, dan metode Bray I untuk penentuan hara P dan K. Perlakuan pemupukan dilakukan dalam skala kecil, dimana tanah perkebunan direparasi dalam wadah polybag berukuran 50 cm x 50 cm. Pemupukan dilakukan selama 4 minggu dengan takaran variasi pupuk setara 0 ton/ha, 10 ton/ha, 25 ton/ha, dan 60 ton/ha. Hasil penelitian menunjukkan bahwa pupuk blotong dapat meningkatkan kadar hara pada tanah perkebunan. Perlakuan 0 ton/ha diperoleh hasil kadar C, N, P, dan K berturut-turut sebesar 1,12%; 0,12%; 102,7588 ppm, dan 101,320 ppm. Perlakuan 10 ton/ha diperoleh hasil kadar berturut-turut sebesar 1,18%; 0,13%; 122,9938 ppm, dan 145,610 ppm. Perlakuan 25 ton/ha diperoleh hasil kadar berturut-turut sebesar 1,22%; 0,14%; 144,8662 ppm, dan 260,960 ppm. Perlakuan 60 ton/ha kadar berturut-turut sebesar 2,58%; 0,15%; 190,6140 ppm, dan 380,180 ppm. Hal tersebut menunjukkan bahwa takaran setara 60 ton/ha cukup untuk meningkatkan kandungan hara C, N, P, dan K tanah dalam waktu 4 minggu. Kata kunci: Blotong, tanah, C-organik, N, P, K ABSTRACT Blotong or filter cake is sugar cane sap dirt from the sugar-making process. However, blotong can be used as an organic fertilizer because the nutrient content in blotong is relatively high. For example, the contents of C, N, P, and K can be a source of nutrients and improve soil quality. This study aimed to determine the increase in nutrients C, N, P, and K in the soil after applying blotong fertilizer. There were methods used in this study, such as the Walkley and Black method for determining C nutrients, the Kjeldahl method for determining N nutrients, and the Bray I method for determining P and K nutrients. Fertilization treatment was carried out on a small scale, where who repaired the plantation soil in polybags measuring 50 cm x 50 cm. Fertilization is carried out for four weeks with varying doses of fertilizer equivalent to 0 tons/ha, 10 tons/ha, 25 tons/ha, and 60 tons/ha. The results showed that blotong fertilizer could increase the nutrient content of the plantation soil. Treatment of 0 ton/ha resulted in C, N, P, and K of 1.12%, 0.12%, 102.7588 ppm, and 101.320 ppm, respectively, while the 10 ton/ha treatment yielded 1.18%, 0.13%, 122.9938 ppm, and 145.610 ppm, respectively. Moreover, the 25 ton/ha treatment produced a grade of 1.22%, 0.14%, 144.8662 ppm, and 260.960 ppm, respectively, whereas the treatment of 60 tons/ha of 2.58%, 0.15%, 190.6140 ppm, and 380.180 ppm successively. These results showed that the equivalent dose of 60 tons/ha was sufficient to increase the contents of C, N, P, and K nutrients in the soil within four weeks. Keywords: blotong, soil, C-organic, N, P, K