Humadi, Jasim
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Development of new effective activated carbon supported alkaline adsorbent used for removal phenolic compounds Humadi, Jasim; Nawaf, Amer T.; Khamees, Luay Ahmed; Abd-Alhussain, Yasser A.; Muhsin, Hussain F.; Ahmed, Mustafa A.; Ahmed, Marwan M.
Communications in Science and Technology Vol 8 No 2 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.2.2023.1244

Abstract

Phenolic (phenol) compounds are the major contaminates in wastewater, which can have a considerable negative influence on the environment and health of human. Adsorption is an efficient process that is widely applied in order to eliminate phenol in wastewater. In recent, Adsorption process has acquired a lot of attentiveness owing to its relative moderate operating conditions. However, adsorption process needs considerable ameliorations in terms of adsorbent modification, process type, productivity, and conversion rate. This work studies the development of a fast and effective adsorption process in a fixed bed adsorption column (FBAC) in order to reach safe and continuous elimination of phenolic compounds. Several adsorption parameters (reaction temperature, adsorbent bed height, feed flow rate and kind of adsorbent) were studied to achieve the highest removal of phenolic compounds. The adsorption process was conducted in the presence of two type of adsorbents (activated carbon (AC), and KOH/AC), 73% and 94% of phenol elimination were attained, respectively, at 10 cm bed height, 1 ml/s feed flow rate, and 75 °C reaction temperature. The adsorbents activity was investigated after six consecutive adsorption cycles at the best process conditions, and the adsorbents show high stability in terms of phenolic compounds adsorption. After that, the spent adsorbents were regenerated by utilizing various solvents (methanol, ethanol and iso-octane), and the results show that iso- octane achieved highest regeneration efficiency. The adsorption process was implemented in the adsorption column that the performance is possibly to be adjusted at an industrial scale since it can be scaled up predictably.
Exploring Fluidization Dynamics and Chemical Performance in Silicon Tetrachloride (SiCl4) Hydrochlorination Processes within a Fluidized Bed Reactor: Development and Analysis of an Eulerian-Granular Model Rasheed, Ekehwanh; Saleh, Saad Nahi; Humadi, Jasim
Communications in Science and Technology Vol 10 No 2 (2025)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.10.2.2025.1741

Abstract

The present work examines the complex fluidization pattern and reactive interactions of silicon tetrachloride (SiCl4) during hydrochlorination in a fluidized-bed reactor (FBR), a system that remains difficult to model accurately. To address this gap, we develop a new Eulerian–granular CFD framework that for the first time couples the Eulerian–Eulerian fluid model with KTGF specifically for SiCl4 hydrochlorination, enabling prediction capabilities that are unavailable in previous FBR studies. The validity of the model was confirmed through comparisons with empirical bed-expansion correlations and Hsu’s gas-temperature data, that demonstrated strong agreement and the ability of the model to capture the coupled thermal–hydrodynamic behavior of the system. In addition to the conventional observations documented in previous studies, this study identifies distinct flow-regime transitions and bed-voidage evolution that are unique to SiCl4. These findings demonstrated the impact of SiCl4’s reactive transport behavior on fluidization stability. Under bubbling conditions, the model uncovered a characteristic SiCl4 distribution pattern that more significantly enhanced gas–solid mixing in comparison to previous report. Additionally, it predicts rapid heat equilibration within ~10 mm of bed height - a behavior not documented in earlier hydrochlorination studies. Chemically, the model predicted a maximum SiHCl3 concentration of 13.08% and an SiCl4 conversion of 28.97%, thereby offering new mechanistic insight into how fluidization dynamics directly govern reaction performance. Overall, this work provides the first specialized CFD framework for SiCl4 hydrochlorination, thus establishing a novel mechanistic understanding of its fluidization–reaction coupling. Furthermore, it offers a more accurate predictive basis for optimizing industrial FBR systems employed in silicon-based chemical manufacturing.