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All Journal Jurnal Rekayasa Bahan Alam dan Energi Berkelanjutan FLUIDA
Eko Andrijanto
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Chemical Engineering, Chemistry & Bioengineering Chemistry Energy Engineering Environmental Science Materials Science & Nanotechnology

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Lithium Recovery Using Hydrogen Manganese Oxide Adsorbent Derived from Spinel Lithium Manganese Oxide : Pemulihan Litium Menggunakan Adsorben Hidrogen Mangan Oksida Berasal dari Spinel Litium Mangan Oksida Widyabuningsih, Dewi; Hielwana, Hanadia; Pauti, Ekbar; Ridwan, Iwan; Rispiandi, Rispiandi; Eko Andrijanto
Jurnal Rekayasa Bahan Alam dan Energi Berkelanjutan Vol. 7 No. 1 (2023)
Publisher : Fakultas Teknik, Universitas Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/ub.rbaet.2023.007.01.05

Abstract

Lithium recovery from brine is recently attracting significant attention due to increasing industrial demand for energy storage, such as batteries. The lithium recovery from lithium brine was investigated using hydrogen manganese oxide adsorbent. The hydrogen manganese oxide adsorbent HMn2O4 (HMO) is derived from the spinel lithium manganese oxide  (LMO), which is synthesized from  LiOH and MnO2 precursor through the reflux method. The synthesized adsorbent was characterized using Scanning Electron Microscopy to identify its physical characteristics and its surface morphology. The adsorption capacity toward lithium solution was performed through an ion exchange process, and the adsorption values were determined using Atomic Absorption Spectroscopy (AAS). The synthesized HMO has a high lithium adsorption capacity for lithium-ion, which is 23 mg/g, and 10 mg/g for desorption. The optimum uptake capacity of HMn2O4 is 44% of the initial values (52 ppm) after 120 minutes of contact time. The synthesized hydrogen manganese oxide adsorbent has a potential industrial lithium recovery for large-scale application.
Effectiveness of Silica Sulphate Catalyst Based on Rice Husk Ash in The Oleic Acid Esterification Process Lidya Elizabeth; Ade Rifqi Maulana; Dwi Febriani, Anisa; Saripudin; Eko Andrijanto
Fluida Vol. 17 No. 2 (2024): FLUIDA
Publisher : Department of Chemical Engineering, Politeknik Negeri Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35313/fluida.v17i2.5279

Abstract

Rice husk contains a lot of silica, so it is widely used as research material. One example is as a raw material for the synthesis of silica sulfate. Silica sulfate was synthesized using the sol-gel method with an impregnation time of 6 hours and 2 hours of calcination with variations in calcination temperature of 400-800oC. The analysis carried out on the silica sulfate catalyst is the analysis of acid concentration and FTIR. The best acid concentration results were 0.86 mmol/gram at 400oC. Characterization with FTIR showed similar peaks between silica and silica sulfate. The -OH and Si-O groups appeared at the peak of the analysis results, indicating that the synthesis of silica from rice husk had been carried out successfully. Modifying silica with sulfuric acid is not obvious through FTIR because the S-OH groups of sulfate ions overlap with the silica atoms in siloxane. The resulting silica sulfate is used as a catalyst in the esterification reaction of oleic acid with methanol. The esterification process was carried out at 60oC and varied with independent variables, namely catalyst loading (5-10%-b), time (2-4 hours), and molar ratio (1:6-1:12). The experimental design was determined using the Response Surface Method (RSM) using Design Expert. From the study results, the best variation obtained was a conversion of 87.03% with a variation of catalyst loading of 7.5%-b, a time of 4 hours, and a molar ratio of 1:12.
Co-Authors Ade Rifqi Maulana Dwi Febriani, Anisa Elizabeth, Lidya Hielwana, Hanadia Iwan Ridwan Pauti, Ekbar Rispiandi Rispiandi Saripudin Saripudin Widyabuningsih, Dewi