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Improvement in Physical Properties of MMA Grafted Coir Fibres Lakshmi, N. S.; Babu, Sarika; Sebastian, Sumy; Ravi, P. K.
International Coconut Community Journal Vol 31 No 2 (2015): CORD
Publisher : International Coconut Community

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (410.372 KB) | DOI: 10.37833/cord.v31i2.56

Abstract

This work deals with the surface modification of Coir fibre through graft copolymerization process. Graft copolymerization of methyl methacrylate (MMA) onto coir fibre was carried out with Potassium per sulphate (PPS) as an initiator under the catalytic influence of Ferrous ammonium sulphate (FAS) in aqueous medium. Control and grafted coir fibres were subjected to evaluation of properties like tensile strength, flexural rigidity, density, water absorbance and light fastness studies. It was observed that MMA grafted coir fibre shows more resistance towards water and light fastness when compared with that of control coir fibre. Further morphological, structural changes and thermal stability of control and grafted coir fibre have also been studied by SEM and TGA techniques. For statistical significance the Analysis of variance (ANOVA) were studied and the P values obtained were less than 0.05 which revealed that the value was highly significant for the improvement of physical properties on coir fibre by graft Co- polymerization.
Low Temperature Grafting of MMA on to Coir Fibre Lakshmi, N. S.; Babu, Sarika; Sebastian, Sumy; Ravi, P. K.
International Coconut Community Journal Vol 31 No 1 (2015): CORD
Publisher : International Coconut Community

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (446.907 KB) | DOI: 10.37833/cord.v31i1.65

Abstract

Low temperature grafting of methyl methacrylate (MMA) on to coir fibre was carried out in aqueous medium using Potassium per sulphate (PPS) as an initiator under the catalytic influence of Ferrous ammonium sulphate (FAS). Optimization of various parameters of grafting viz. monomer, initiator and catalyst concentration, time and temperature was carried out to obtain the maximum tensile properties. Evidence of grafting was characterized from Fourier Transform Infrared spectroscopy (FTIR), Scanning Electron Microscopy (SEM) and Thermal analysis (TGA). The maximum breaking stress (BS) of control and grafted coir fibre were 213.08 and 365.00 N/mm2 respectively. Hence the percentage of improvement of grafted coir fibre was found to be 71.30%. Increase in tensile properties with maximum BS observed under monomer (25%), initiator (0.75%) and catalyst (0.75%) concentration, time (150min) and temperature (500C) respectively. The t-test and Analysis of variance (ANOVA) were studied for statistical significance and the P values obtained were less than 0.05 which revealed that the value was highly significant for the improvement of mechanical strength on coir fibre by graft Co- polymerization.