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Evaluation of Mineral-Based Zn-Doped Hydroxyapatite as a Photocatalyst for Methylene Blue Degradation Nisrina, Aniqa; Karya, Teguh; Halim, Riyan; Murniati, Anceu; Hardian, Arie; Gustaman Syarif, Dani; Rostika Noviyanti, Atiek; Jasmansyah, Jasmansyah; Reza, Muhammad
The Journal of Pure and Applied Chemistry Research Vol. 13 No. 3 (2024): Edition September-December 2024
Publisher : Chemistry Department, The University of Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/ub.jpacr.2024.013.03.7908

Abstract

Methylene blue is a synthetic dye known to be harmful to aquatic environments. Therefore, efforts are needed to minimize methylene blue waste. This study focuses on degrading methylene blue through photocatalysis, a method chosen for its affordability and ease of use. The photocatalyst used is hydroxyapatite (HAp) derived from limestone (CaCO3) doped with zinc ions (Zn2+). This combination enhances the efficiency of breaking down dye molecules in liquid waste. The photocatalytic performance was tested under three variations: solution concentration, contact time, and pH, using an 8-watt UV lamp for specified durations. Solution absorbance was measured using a Shimadzu 1800 UV-Vis spectrophotometer. Optimal conditions for methylene blue photodegradation by Zn-doped HAp were achieved at 67.2% efficiency for 5 ppm concentration, 16.125% for 120 minutes of irradiation, and 34.86% at pH 7. Additionally, the study included an analysis of adsorption isotherm models for concentration variation and kinetic adsorption analysis for time variation. The Langmuir and Temkin adsorption isotherm models were found to be most suitable with an R2 = 1. The photodegradation kinetics model followed pseudo second-order kinetics with an R2 = 0.990.
EVALUATION OF MINERAL-BASED HYDROXYAPATITE/ZnO COMPOSITES AS PHOTOCATALISTS FOR METHYLEN BLUE DEGRADATION Hardian, Arie; Nafisah, Aulia Zakiyatun; Karya, Teguh; Halim, Riyan; Murniati, Anceu; Syarif, Dani Gustaman; Noviyanti, Atiek Rostika; Nurhayati, Mita; Jasmansyah, Jasmansyah; Reza, Muhammad
al Kimiya: Jurnal Ilmu Kimia dan Terapan Vol 11, No 2 (2024): al Kimiya: Jurnal Ilmu Kimia dan Terapan
Publisher : Department of Chemistry, Faculty of Science and Technology, UIN Sunan Gunung Djati Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15575/ak.v11i2.37886

Abstract

The use of dyes in the textile industry has increased significantly, raising concerns about their potential to pollute the environment and harm human health. Methylene blue is a widely used synthetic dye, necessitating effective methods for its degradation. Photodegradation is a promising approach to decompose dyes into simpler, less harmful compounds. In this study, hydroxyapatite combined with ZnO was employed as a photocatalyst material to enhance photocatalytic performance. The research aims to degrade methylene blue using a Hydroxyapatite/ZnO (HAp/ZnO) nanocomposite through photodegradation. The optimization of the photodegradation process was investigated by varying irradiation time, methylene blue concentration, and pH. The optimum degradation of methylene blue was achieved using 20 mg of HAp/ZnO nanocomposite at an irradiation time of 120 minutes, an initial methylene blue concentration of 5 ppm, and pH 7. Adsorption isotherm modeling revealed that the process followed the Langmuir isotherm model, with a maximum adsorption capacity (qmax) of 0.3353 mg/g. The degradation followed pseudo-second-order kinetics with a reaction rate constant of 4.0026×105 L/mol·s.
Kedudukan Teori Filsafat Manajemen Ilmu Dalam Islam Dan Implementasinya Di SMAIT Insan Cita Serang Supian, Sopwan; Wahyudi, Yudi; Karya, Teguh; Hidayat, Wahyu; Fauzi, Anis
Journal Of Human And Education (JAHE) Vol. 3 No. 4 (2023): Journal Of Human And Education (JAHE)
Publisher : Universitas Pahlawan Tuanku Tambusai

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31004/jh.v3i4.451

Abstract

Kedududukan Filsafat dalam Islam mengalami pasang surut, sebagian ulama dan ilmuwan berpendapat bahwa Islam dan filsafat berbeda, dimana Islam dan filsafat mempunyai domain yang tidak bisa disatukan. Namun tidak sedikit pula yang mencoba mensintesakan dan mengharmoniskan keduanya, kajian ini menjelaskan bahwa filsafat dan agama Islam memiliki keterkaitan yang erat yang saling melengkapi sebagai bagian dari ilmu pengetahuan. Kemudian bagaimanakah teori manajemen dan bagaimanakah kedudukan filsafat Ilmu dalam Islam? Tujuan dari penelitian ini adalah menganlisis teori filsafat manajemen dan mengimplementasikannya di SMAIT Insan Cita Serang. Dalam penyusunan artikel ini, metodologi penelitian yang diterapkan ialah penelitian kepustakaan (library research) dan studi kasus (case study) yang merupakan salah satu jenis penelitian yang dapat menjawab beberapa issue atau objek akan suatu fenomena terutama di dalam cabang ilmu sosial. Penelitian kasus digunakan sebagai desain penelitian kualitatif untuk mengevaluasi kejadian atau situasi dalam dunia nyata (real situation). Hasil dari penelitian ini adalah menganalisa kedudukan filsafat ilmu manajemen dan implementasinya di SMAIT Insan Cita Serang.
EVALUATION OF MINERAL-BASED HYDROXYAPATITE/ZnO COMPOSITES AS PHOTOCATALISTS FOR METHYLEN BLUE DEGRADATION Hardian, Arie; Nafisah, Aulia Zakiyatun; Karya, Teguh; Halim, Riyan; Murniati, Anceu; Syarif, Dani Gustaman; Noviyanti, Atiek Rostika; Nurhayati, Mita; Jasmansyah, Jasmansyah; Reza, Muhammad
al Kimiya: Jurnal Ilmu Kimia dan Terapan Vol. 11 No. 2 (2024): al Kimiya: Jurnal Ilmu Kimia dan Terapan
Publisher : Department of Chemistry, Faculty of Science and Technology, UIN Sunan Gunung Djati Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15575/ak.v11i2.37886

Abstract

The use of dyes in the textile industry has increased significantly, raising concerns about their potential to pollute the environment and harm human health. Methylene blue is a widely used synthetic dye, necessitating effective methods for its degradation. Photodegradation is a promising approach to decompose dyes into simpler, less harmful compounds. In this study, hydroxyapatite combined with ZnO was employed as a photocatalyst material to enhance photocatalytic performance. The research aims to degrade methylene blue using a Hydroxyapatite/ZnO (HAp/ZnO) nanocomposite through photodegradation. The optimization of the photodegradation process was investigated by varying irradiation time, methylene blue concentration, and pH. The optimum degradation of methylene blue was achieved using 20 mg of HAp/ZnO nanocomposite at an irradiation time of 120 minutes, an initial methylene blue concentration of 5 ppm, and pH 7. Adsorption isotherm modeling revealed that the process followed the Langmuir isotherm model, with a maximum adsorption capacity (qmax) of 0.3353 mg/g. The degradation followed pseudo-second-order kinetics with a reaction rate constant of 4.0026×105 L/mol·s.