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All Journal Bulletin of Chemical Reaction Engineering & Catalysis
Bui Bao Long, Pham
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Chemical Engineering, Chemistry & Bioengineering Chemistry

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Effect of the Dimethylformamide/Isopropanol Solvent Ratio on the Structure, Optical Properties, and Photodegradation Performance of RhB Using Bi-MOF Bui Bao Long, Pham; Nguyen, Van Cuong; Pham, Hoang Ai Le; Ta, Qui Thanh Hoai; Dang, Huu Phuc
Bulletin of Chemical Reaction Engineering & Catalysis 2025: BCREC Volume 20 Issue 1 Year 2025 (April 2025)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20345

Abstract

This study investigated the structural characteristics, surface morphology, and photocatalytic activity of bismuth-based metal-organic frameworks (BiBTC-ISOx) synthesized with varying ratios of N, N-dimethylformamide (DMF) and isopropanol (ISO). X-ray diffraction confirmed the crystalline structure of the BiBTC-ISOx (x = 1, 3, 6) compounds, while FTIR spectroscopy verified the successful bonding between the ligand and the Bi3+ complex. UV-Vis spectroscopy revealed strong UV light absorption with tunable bandgaps ranging from 3.28 to 3.68 eV. Nitrogen adsorption/desorption analysis revealed a hierarchical micro/mesoporous structure, with BiBTC-ISO6 exhibiting the highest surface area (24.968 m2/g). SEM imaging revealed a rectangular rod-like morphology, which became more elongated with increasing ISO content. The photocatalytic activity of BiBTC-ISOx was evaluated based on the degradation of Rhodamine B (RhB) under visible light, with BiBTC-ISO6 demonstrating the highest efficiency. Optimal conditions for RhB degradation were determined to be 0.03 g catalyst mass, 10 ppm RhB concentration, and pH of 3. Mechanistic studies revealed that superoxide radicals are the primary active species in the photocatalytic process. The BiBTC-ISO6 catalyst exhibited excellent stability and reusability over three consecutive degradation cycles, highlighting its potential for practical applications in organic dye removal. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
Co-Authors Dang, Huu Phuc Nguyen, Van Cuong Pham, Hoang Ai Le Ta, Qui Thanh Hoai