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Adsorben Berbasis Campuran Andisol/Zeolit/Karbon Aktif untuk Penjernihan Air Gambut Devi Asriani; Pranoto Pranoto; Edi Pramono; Ozi Adi Saputra
ALCHEMY Jurnal Penelitian Kimia Vol 21, No 1 (2025): March
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.21.1.85539.138-148

Abstract

Andisol, karbon aktif, dan zeolit memiliki luas permukaan, porositas, dan kapasitas tukar ion yang efektif dalam menyerap kontaminan air. Penelitian ini bertujuan untuk mempelajari pembuatan adsorben berbasis andisol/zeolite/active carbon dilanjutkan dan kinerja adsorpsi serta parameter kinetika adsorpsinya untuk penjernihan air gambut. Tanah andisol dan zeolit diaktivasi dengan larutan NaOH 3 M dan komposisi tanah andisol, zeolit, dan karbon aktif divariasikan dengan perbandingan berat 100:0:0; 0:100:0; 0:0:100; 50:25:25; 25:50:25; dan 25:25:50 (b/b). Data menunjukkan kapasitas adsorpsi terbesar dihasilkan oleh komposisi tanah andisol:zeolit:karbon aktif pada komposisi 25:50:25 yaitu 39,67 mg/g dengan persentase penghilangan sebesar 81,72%. Isoterm adsorpsi mengikuti isoterm Redlich-Peterson. Analisis kinetika menunjukkan bahwa adsorpsi mengikuti model kinetika pseudo orde dua dengan konstanta laju adsorpsi sebesar 0,32 g∙mg-1min-1 dan qe sebesar 5,38 mg/g. Berdasarkan hasil tersebut campuran tanah andisol/zeolite/karbon aktif berpotensi digunakan sebagai absorben dalam penjernihan air gambut.Andisol/Zeolite/Active Carbon-based Adsorbent for Peat Water Treatment. Andisol, Activated Carbon, and Zeolite have a high specific surface area, porosity, and ion exchange capacity, effectively absorbing water impurities. This study aims to study the andisol/zeolite/active carbon-based adsorbent preparation and its adsorption capacity for peat water treatment. Andisol soil and zeolite were activated with NaOH 3 M solution and the composition of Andisol Soil/Zeolite/Activated Carbon were varied of 100:0:0; 0:100:0; 0:0:100; 50:25:25; 25:50:25; and 25:25:50 (wt%). Data shows that the largest adsorption capacity obtained for Andisol/Zeolite/Activated Carbon composition of 25:50:25 (wt%) of 39.67 mg/g and 81.72% for removal percentage. The isotherm adsorption followed Redlich-Peterson isotherm. The kinetics analysis showed that the adsorption followed the pseudo-second-order kinetics model with an adsorption rate constant of 0.32 g∙mg-1min-1 and qe of 5.38 mg/g. Based on these results, the mixture of andisol soil/zeolite/activated carbon has the potential to be used as an absorbent in peat water purification.
Preparation and Optimization of Coal Fly Ash-Based Geopolymer and Its Application as an Adsorbent for Basic Yellow 2 and Methylene Blue Dyes Eddy Heraldy; Edi Pramono; Yuniawan Hidayat; Khoirina Dwi Nugrahaningtyas; Angel Maydeleine; Intan Dwi Rahmadani
ALCHEMY Jurnal Penelitian Kimia Vol 22, No 1 (2026): March
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.22.1.98784.254-263

Abstract

The preparation of geopolymer from coal fly ash (CFA) solid waste of Jepara PLTU has been carried out by activating CFA using a 10 M NaOH solution and Na2SiO3. Characterization of CFA and geopolymer using X-ray fluorescence (XRF), X-ray diffractometer (XRD), Scanning Electron Microscopy (SEM), and Fourier Transform Infra-Red (FTIR) spectroscopy. The adsorption process was studied under parameters including pH, geopolymer mass, contact time, and initial adsorbate concentration. The optimum conditions for the adsorption process of basic yellow 2 dye with fly ash-based geopolymer were optimum at solution pH of 11; adsorbent mass of 0.15 g; contact time of 120 minutes; and initial concentration of 80 ppm, while methylene blue adsorption was at solution pH of 11; adsorbent mass of 0.15 g; contact time of 120 minutes; and initial concentration of 60 ppm. Coal fly ash, a solid waste product from the Jepara PLTU, can be used to produce geopolymers through geopolymerization in the presence of activators such as NaOH and Na₂SiO₃. The adsorption capacities of these geopolymers for basic yellow 2 and methylene blue dye solutions are 26.55 and 19.825 mg/g, respectively.