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Removal of Heavy Metals: Pb(II), Ni(II) And Cd(II) By Fe3O4@SiO2-TMPDT Adsorbent Prepared From Rice Husk Ash Sri Hastuti; Tri Martini; Atmanto Heru Wibowo; Dina Fitriana; Wihda Zuhara; Hesti Mutma'inah; Rima Indriyana Putri
ALCHEMY Jurnal Penelitian Kimia Vol 21, No 1 (2025): March
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.21.1.91934.53-63

Abstract

The adsorption of Pb(II), Ni(II), and Cd(II) metal ions onto Fe3O4@SiO2-TMPDT adsorbent was carried out through batch experiments. In this study, Fe3O4@SiO2-TMPDT adsorbent was synthesized through a sol-gel process using sodium silicate extracted from rice husk ash (Na2SiO3)RHA with the addition of magnetite (Fe3O4) and modifier N1-(3-trimethoxysilylpropyl) diethylenetriamine (TMPDT). The synthesized adsorbent was then characterized by FTIR. The Fe3O4@SiO2-TMPDT adsorbent was prepared with suspension Fe3O4:(Na2SiO3)RHA ratios (v/v) of 1:4, 2:3, and 1:1, and varying the amounts of TMPDT of 1; 2.5 and 5 mL. The optimum pH to perform conditions adsorption for Pb(II) metal ions was determined to be 4, while Ni(II) and Cd(II) were 5. In addition, the adsorption process followed a pseudo-second-order kinetic model, and the adsorption isotherm was consistent with the Langmuir isotherm. The adsorption capacities for Pb(II), Ni(II), and Cd(II) were 11.760 mg/g, 1.864 mg/g, and 1.888 mg/g, respectively.